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https://olympias.lib.uoi.gr/jspui/handle/123456789/9582Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Bilis, G. | en |
| dc.contributor.author | Louloudi, M. | en |
| dc.date.accessioned | 2015-11-24T16:50:14Z | - |
| dc.date.available | 2015-11-24T16:50:14Z | - |
| dc.identifier.issn | 1565-3633 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9582 | - |
| dc.rights | Default Licence | - |
| dc.subject | olefin cis-dihydroxylation | en |
| dc.subject | dioxygen activation | en |
| dc.subject | hydrogen-peroxide | en |
| dc.subject | methane monooxygenase | en |
| dc.subject | intermediate | en |
| dc.subject | chemistry | en |
| dc.subject | models | en |
| dc.subject | epoxidation | en |
| dc.subject | proteins | en |
| dc.subject | enzymes | en |
| dc.title | The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon Oxidation | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | Doi 10.1155/2010/861892 | - |
| heal.identifier.secondary | <Go to ISI>://000280798200001 | - |
| heal.identifier.secondary | http://downloads.hindawi.com/journals/bca/2010/861892.pdf | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2010 | - |
| heal.abstract | A detailed catalytic study of LFe(III)Cl (where L = 3-{2-[2-(3-hydroxy-1,3-diphenyl-allylideneamino)-ethylamino]-ethylimino}-1,3-diphenyl-propen-1-ol) for hydrocarbon oxidation was carried out, focusing on the role of solvent, atmospheric dioxygen, and oxidant on catalytic efficiency. The data showed that LFe(III)Cl catalyst was efficient in homogeneous hydrocarbon oxidations providing significant yields. Moreover, tert-BuOOH provided comparable oxidation yields with H(2)O(2), slightly favoring the formation of alcohols and ketones versus epoxides. Dioxygen intervened in the catalytic reaction, influencing the nature of oxidation products. The polarity of solvent strongly influenced the reaction rates and the nature of oxidation products. A mechanistic model is postulated assuming that LFe(III)Cl functions via the formation of iron-hydroperoxo-species, followed by a radical-based mechanistic path. | en |
| heal.publisher | Hindawi Publishing Corporation | en |
| heal.journalName | Bioinorg Chem Appl | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Bilis-2010-The Catalytic Functi.pdf | 758.06 kB | Adobe PDF | View/Open |
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