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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/9909
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dc.contributor.authorAlexandropoulos, D. I.en
dc.contributor.authorPapatriantafyllopoulou, C.en
dc.contributor.authorLi, C. R.en
dc.contributor.authorCunha-Silva, L.en
dc.contributor.authorManos, M. J.en
dc.contributor.authorTasiopoulos, A. J.en
dc.contributor.authorWernsdorfer, W.en
dc.contributor.authorChristou, G.en
dc.contributor.authorStamatatos, T. C.en
dc.date.accessioned2015-11-24T16:52:36Z-
dc.date.available2015-11-24T16:52:36Z-
dc.identifier.issn1434-1948-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9909-
dc.rightsDefault Licence-
dc.subjectcluster compoundsen
dc.subjectcyanatesen
dc.subjectmanganeseen
dc.subjectn,o ligandsen
dc.subjectsingle-molecule magnetsen
dc.subjectspin-stateen
dc.subjectsingleen
dc.subjectligandsen
dc.subjectcrystalen
dc.subjectcomplexesen
dc.subjectazideen
dc.titleApproaches to Molecular Magnetic Materials from the Use of Cyanate Groups in Higher Oxidation State Metal Cluster Chemistry: Mn14 and Mn16en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1002/ejic.201300099-
heal.identifier.secondary<Go to ISI>://000318167500002-
heal.identifier.secondaryhttp://onlinelibrary.wiley.com/store/10.1002/ejic.201300099/asset/2286_ftp.pdf?v=1&t=hmu92768&s=45a6f63ce1b29ec699ac184c36a3ef3e7d1fa990-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2013-
heal.abstractThe initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded structurally interesting MnII/III14 and MnII/III/IV16 clusters, respectively. In both complexes, the end-on bridging cyanato groups show an obvious preference in binding through their O atom, a significantly different ligation than that for the homoatomic-type N3 ligand. The Mn14 compound shows entirely visible out-of-phase signals below 5 K and large hysteresis loops below 2 K.en
heal.publisherWiley-VCH Verlagen
heal.journalNameEuropean Journal of Inorganic Chemistryen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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