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dc.contributor.authorSakellarides, T. M.en
dc.contributor.authorSakkas, V. A.en
dc.contributor.authorLambropoulou, D. A.en
dc.contributor.authorAlbanis, T. A.en
dc.date.accessioned2015-11-24T16:52:32Z-
dc.date.available2015-11-24T16:52:32Z-
dc.identifier.issn0306-7319-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9900-
dc.rightsDefault Licence-
dc.subjectphotocatalytic studiesen
dc.subjecttio2en
dc.subjectsolid-phase microextractionen
dc.subjectfenitrothionen
dc.subjectmethyl parathionen
dc.subjectorganophosphorus insecticidesen
dc.subjectnatural-watersen
dc.subjectdegradationen
dc.subjectpesticidesen
dc.subjectextractionen
dc.subjectoxidationen
dc.subjectremovalen
dc.subjecttransformationen
dc.subjectchromatographyen
dc.subjectmetabolitesen
dc.titleApplication of solid-phase microextraction (SPME) for photocatalytic studies of fenitrothion and methyl parathion in aqueous TiO2 suspensionsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1080/03067310310001597617-
heal.identifier.secondary<Go to ISI>://000186506700017-
heal.identifier.secondaryhttp://www.tandfonline.com/doi/pdf/10.1080/03067310310001597617-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2004-
heal.abstractThe photocatalytic degradation of the organophosphorus insecticides fenitrothion and methyl parathion has been studied in aqueous titanium dioxide TiO2 suspensions under simulated solar irradiation. The degradation kinetics followed a pseudo-first-order reaction and has been monitored by headspace solid-phase microextraction (HS-SPME) and gas chromatographic techniques (GC-FTD). Degradation of both insecticides has been a rapid process with half-lives varied between 3.7 and 12.9 min depending on the TiO2 concentration as well as on the structure of the compound. The generated transformation by-products formed during the process were extracted by SPME used in two approaches: (a) by direct immersion in the filtered sample and (b) by exposing the fiber in the sample headspace. The intermediates were formed predominately via oxidation processes and were identified by gas chromatography and mass spectroscopy techniques.en
heal.publisherTaylor & Francisen
heal.journalNameInternational Journal of Environmental Analytical Chemistryen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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