Please use this identifier to cite or link to this item:
https://olympias.lib.uoi.gr/jspui/handle/123456789/9793Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Nikolakis, V. A. | en |
| dc.contributor.author | Exarchou, V. | en |
| dc.contributor.author | Jakusch, T. | en |
| dc.contributor.author | Woolins, J. D. | en |
| dc.contributor.author | Slawin, A. M. Z. | en |
| dc.contributor.author | Kiss, T. | en |
| dc.contributor.author | Kabanos, T. A. | en |
| dc.date.accessioned | 2015-11-24T16:51:51Z | - |
| dc.date.available | 2015-11-24T16:51:51Z | - |
| dc.identifier.issn | 1477-9226 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9793 | - |
| dc.rights | Default Licence | - |
| dc.subject | modeling supramolecular interactions | en |
| dc.subject | density-functional theory | en |
| dc.subject | human-serum transferrin | en |
| dc.subject | vanadium complexes | en |
| dc.subject | solid-state | en |
| dc.subject | metal-complexes | en |
| dc.subject | in-vitro | en |
| dc.subject | structural-characterization | en |
| dc.subject | dependent haloperoxidases | en |
| dc.subject | coordination-compounds | en |
| dc.title | Tris-(hydroxyamino)triazines: high-affinity chelating tridentate O,N,O-hydroxylamine ligand for the cis-V(V)O(2)(+) cation | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | <Go to ISI>://000282006200023 | - |
| heal.identifier.secondary | http://pubs.rsc.org/en/content/articlepdf/2010/dt/c0dt00574f | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2010 | - |
| heal.abstract | The treatment of the trichloro-1,3,5-triazine with N-methylhydroxylamine hydrochloride results in the replacement of the three chlorine atoms of the triazine ring with the function -N(OH)CH(3) yielding the symmetrical tris-(hydroxyamino) triazine ligand H(3) trihyat. Reaction of the ligand H(3) trihyat with NaV(V)O(3) in aqueous solution followed by addition of Ph(4)PCl gave the mononuclear vanadium(V) compound Ph(4)P[V(V)O(2)(Htrihyat)] (1). The structure of compound 1 was determined by X-ray crystallography and indicates that this compound has a distorted square-pyramidal arrangement around vanadium. The ligand Htrihyat(2-) is bonded to vanadium atom in a tridentate fashion at the triazine ring nitrogen atom and the two deprotonated hydroxylamido oxygen atoms. The high electron density of the triazine ring nitrogen atoms, which results from the resonative contribution of electrons of exocyclic nitrogen atoms, leads to a very strong V-N bond. The cis-[V(V)O(2)(Htrihyat)](-) species exhibits high hydrolytic stability in aqueous solution over a wide pH range, 2.5-11.5, as was evidenced by potentiometry. | en |
| heal.publisher | Royal Society of Chemistry | en |
| heal.journalName | Dalton Transactions | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Nikolakis-2010-Tris-(hydroxyamino)t.pdf | 397.09 kB | Adobe PDF | View/Open Request a copy |
This item is licensed under a Creative Commons License
