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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | A. Antos, | en |
| dc.contributor.author | Y. Elemes, | en |
| dc.contributor.author | A. Michaelides, | en |
| dc.contributor.author | J. A. Nyxas, | en |
| dc.contributor.author | S. Skoulika, | en |
| dc.contributor.author | L. P. Hadjiarapoglou | en |
| dc.date.accessioned | 2015-11-24T16:51:03Z | - |
| dc.date.available | 2015-11-24T16:51:03Z | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9680 | - |
| dc.rights | Default Licence | - |
| dc.title | The Question of Electrophilic vs Nucleophilic Addition of Cyclic beta-Dicarbonyl Phenyliodonium Ylides: Electrophilic Cycloaddition of Diphenylketene | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | 10.1021/jo3020787 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/abs/10.1021/jo3020787 | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2012 | - |
| heal.abstract | The reaction of Ξ²-dicarbonyl phenyliodonium ylides with diphenylketene at room temperature affords mixtures of lactone and aurone derivatives. The initial electrophilic attack of the iodonium ylide on the CΞ² position of the diphenylketene, followed by cyclization of the zwitterionic species, and subsequent ejection of iodobenzene, affords the lactone and aurone cycloadducts. Treatment of Ξ²-dicarbonyl iodonium ylides with acyl chlorides yields Ξ±-chloroenones with good to excellent yields. | en |
| heal.publisher | American Chemical Society | en |
| heal.journalName | J. Org. Chem. | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Skoulika-2012-The question of electrophilic.pdf | 322.44 kB | Adobe PDF | View/Open Request a copy |
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