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dc.contributor.authorEconomou, E. D.en
dc.contributor.authorVaimakis, T. C.en
dc.contributor.authorPapamichael, E. M.en
dc.date.accessioned2015-11-24T16:50:51Z-
dc.date.available2015-11-24T16:50:51Z-
dc.identifier.issn0021-9797-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9651-
dc.rightsDefault Licence-
dc.subjectkinetic mechanismen
dc.subjectphosphorite dissolutionen
dc.subjectmodel equationen
dc.subjectcalcite dissolutionen
dc.subjectbeneficiationen
dc.subjectmechanismen
dc.subjectcrystalsen
dc.subjectsystemsen
dc.titleThe kinetics of dissolution of the carbonate minerals of phosphate ores using dilute acetic acid solutions: The case of pH range from 3.96 to 6.40en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1006/jcis.2001.7931-
heal.identifier.secondary<Go to ISI>://000173221900016-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0021979701979317/1-s2.0-S0021979701979317-main.pdf?_tid=dc01e7c2a6f7b598d4680bd0de0e8a6b&acdnat=1333113649_6c24aa15b7fcb794db7ee19d2307e28b-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2002-
heal.abstractIn this manuscript we present, in detail, the mechanism of the selective dissolution of calcite from low-grade phosphate ores (Epirus area, Greece) by dilute acetic acid. It was found that mass transfer makes a significant contribution to the rate-determining step of the overall reaction of four separate pH regions discriminated within the pH range from 3.96 to 6.40. Moreover, two different reaction mechanisms were proposed and two different model equations best fitted the corresponding experimental data. By applying a particular treatment to the developed differential equations proposed by us earlier (see Ref. (2)), we estimated the rate constants of specific slow reactions referred to pH regions 3.96-4.95 and 4.95-5.50. However, for pH region 5.50-6.40, we cannot reach a similar conclusion so far. (C) 2002 Elsevier Science.en
heal.publisherElsevieren
heal.journalNameJ Colloid Interface Scien
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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