Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/9581
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dc.contributor.authorMilaeva, E. R.en
dc.contributor.authorGerasimova, O. A.en
dc.contributor.authorMaximov, A. L.en
dc.contributor.authorIvanova, E. A.en
dc.contributor.authorKarachanov, E. A.en
dc.contributor.authorHadjiliadis, N.en
dc.contributor.authorLouloudi, M.en
dc.date.accessioned2015-11-24T16:50:13Z-
dc.date.available2015-11-24T16:50:13Z-
dc.identifier.issn1566-7367-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9581-
dc.rightsDefault Licence-
dc.subjectsupported metalloporphyrinsen
dc.subject2,6-di-tert-butylphenolen
dc.subjectbiomimetic oxidationen
dc.subjectimidazole propyl gelen
dc.subjecthydrocarbon monooxygenation catalysten
dc.subjectmanganese porphyrinen
dc.subjectpolyvalent porphyrinsen
dc.subjectalkane hydroxylationen
dc.subjectoxidation catalystsen
dc.subjectolefin epoxidationen
dc.subjecthydrogen-peroxideen
dc.subjectcomplexesen
dc.subjectalkeneen
dc.titleThe catalytic activity of immobilized on modified silica metalloporphyrins bearing antioxidative 2,6-di-tert-butylphenol pendantsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.catcom.2007.04.012-
heal.identifier.secondary<Go to ISI>://000251208900040-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1566736707001550/1-s2.0-S1566736707001550-main.pdf?_tid=cd3c92ba-362e-11e3-8036-00000aacb360&acdnat=1381906219_388d0a7b697c7f11e43f985193ca5684-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2007-
heal.abstractA comparative study of the catalytic activity of supported manganese(III) and iron(III) chlorides of meso-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin (R4PMnCl, R4PFeCl) and meso-tetraphenylporphyrin (TPPMnCl, TPPFeCl) is reported. The metalloporphyrins have been immobilized via coordination bond on the surface of two series of imidazole modified silica, imidazole propyl silica (IPS) and imidazole 3-(glycidyloxypropyl) silica (IGOPS). The heterogenised catalysts have been evaluated for hydrocarbon oxidation by sodium periodate. The critical role of 2,6-di-tert-butylphenol groups on the periphery of porphyrin ring in their catalytic activity has been evaluated and pertinent structural and mechanistic aspects are discussed. (C) 2007 Elsevier B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameCatalysis Communicationsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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