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DC Field | Value | Language |
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dc.contributor.author | Assimomytis, N. | en |
dc.contributor.author | Sariyannis, Y. | en |
dc.contributor.author | Stavropoulos, G. | en |
dc.contributor.author | Tsoungas, P. G. | en |
dc.contributor.author | Varvounis, G. | en |
dc.contributor.author | Cordopatis, P. | en |
dc.date.accessioned | 2015-11-24T16:50:05Z | - |
dc.date.available | 2015-11-24T16:50:05Z | - |
dc.identifier.issn | 0936-5214 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9566 | - |
dc.rights | Default Licence | - |
dc.subject | rearrangements | en |
dc.subject | reductions | en |
dc.subject | mannich bases | en |
dc.subject | carbamates | en |
dc.subject | ortho-fries rearrangement | en |
dc.subject | directed ortho-metalation | en |
dc.subject | regiospecific route | en |
dc.subject | organic-synthesis | en |
dc.subject | secondary-amines | en |
dc.subject | ortho-lithiation | en |
dc.subject | tertiary amides | en |
dc.subject | one-pot | en |
dc.subject | reduction | en |
dc.subject | phenols | en |
dc.subject | derivatives | en |
dc.title | Anionic ortho-Fries Rearrangement, a Facile Route to Arenol-Based Mannich Bases | en |
heal.type | journalArticle | - |
heal.type.en | Journal article | en |
heal.type.el | Άρθρο Περιοδικού | el |
heal.identifier.primary | DOI 10.1055/s-0029-1217991 | - |
heal.identifier.secondary | <Go to ISI>://000271904100009 | - |
heal.identifier.secondary | https://www.thieme-connect.de/ejournals/pdf/10.1055/s-0029-1217991.pdf | - |
heal.language | en | - |
heal.access | campus | - |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.publicationDate | 2009 | - |
heal.abstract | Phenol and 1-naphthol-based carbamates undergo the anionic ortho-Fries rearrangement to their corresponding amides. Bulky substitution at position 8 of 1-naphthol-based carbamates makes the rearrangement an exclusive reaction, even at -90 degrees C, under a variety of conditions. The amides can be efficiently reduced to the corresponding Mannich bases. A novel route to 7-[(dialkylamino)methyl]-8-hydroxy-1-naphthaldehydes is presented. | en |
heal.publisher | Thieme Publishing | en |
heal.journalName | Synlett | en |
heal.journalType | peer reviewed | - |
heal.fullTextAvailability | TRUE | - |
Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ |
Files in This Item:
File | Description | Size | Format | |
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Assimomytis-2009-Anionic ortho-Fries.pdf | 143.06 kB | Adobe PDF | View/Open |
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