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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/9536
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dc.contributor.authorG.J. Corban,en
dc.contributor.authorS.K. Hadjikakou,en
dc.contributor.authorN. Hadjiliadis,en
dc.contributor.authorM. Kubicki,en
dc.contributor.authorE.R.t. Ticknik,en
dc.contributor.authorI.S. Butler,en
dc.contributor.authorE. Drougas,en
dc.contributor.authorAgnie M. Kosmasen
dc.date.accessioned2015-11-24T16:49:51Z-
dc.date.available2015-11-24T16:49:51Z-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9536-
dc.rightsDefault Licence-
dc.titleSynthesis, Structural Characterization, and Computational Studies of Novel Diiodine Adducts with the Heterocyclic Thioamides N-Methylbenzothiazole-2-thione and Benzimidazole-2-thione:"‰ Implications with the Mechanism of Action of Antithyroid Drugsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primary10.1021/ic0484396-
heal.identifier.secondaryhttp://pubs.acs.org/doi/abs/10.1021/ic0484396-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2005-
heal.abstractThe reaction of I2 with N-methylbenzothiazole-2-thione and benzimidazole-2-thione produced three new charge-transfer complexes. The X-ray crystal structure of {[(MBZIM)2I]+}Β·[I3-}Β·[(MBZIM)I2] reveals the cocrystallization of both a "�spoke"� and an "�iodonium"� salt. This is the first such crystal structure ever reported and may lead to the conclusion that a "�spoke"� and an iodonium salt equilibrium may also be established in solution. Useful conclusions on the mechanism of action of antithyroid drugs are drawn.en
heal.publisherAmerican Chemical Societyen
heal.journalNameInorg. Chem.en
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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