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dc.contributor.authorYang, S. Y.en
dc.contributor.authorVlessidis, A. G.en
dc.contributor.authorEvmiridis, N. P.en
dc.date.accessioned2015-11-24T16:49:22Z-
dc.date.available2015-11-24T16:49:22Z-
dc.identifier.issn0927-6513-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9473-
dc.rightsDefault Licence-
dc.subjectanalcimeen
dc.subjectferrieriteen
dc.subjectmagadiiteen
dc.subjectoffretiteen
dc.subjectomegaen
dc.subjectwater effecten
dc.subjectzeolite synthesisen
dc.subjectnuclear magnetic-resonanceen
dc.subjectmolecular-sieve synthesisen
dc.subjectnonaqueous synthesisen
dc.subjectsilica-sodaliteen
dc.subjectcrystalsen
dc.subjectomegaen
dc.subjectferrieriteen
dc.subjectchemistryen
dc.subjectspectraen
dc.subjectmazziteen
dc.titleSynthesis of zeolites in the system Na2O-SiO2-Al2O3-H2O glycerolen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1016/S0927-6513(96)00120-4-
heal.identifier.secondary<Go to ISI>://A1997XD80800010-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0927651396001204/1-s2.0-S0927651396001204-main.pdf?_tid=77abcb32-356a-11e3-8cfa-00000aacb35f&acdnat=1381821894_35fadb641633e65069afcd5818bd150d-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1997-
heal.abstractThe synthesis of zeolites from a mixture of a non-aqueous glycerol aluminosilicate gel and a controlled quantity of water has been studied. It was found that a minimum water content in the synthesis mixture is required to achieve a measurable crystallization rate. A further increase of the water content may facilitate the crystallization process of omega and then switch the crystal structure of the product from omega to analcime. At the Si/Al ratio of 6.95 in the synthesis mixture an increase of the NaOH content leads to a product sequence of amorphous-->omega-->analcime-->analcime and sodalite. An increase of the Si/Al ratio in the synthesis mixture leads to a product sequence of sodalite-->omega(+ analcime)-->ferrierite-->magadiite. At the Si/Al ratio of 6.95 in the synthesis mixture a change of the alkali cations in a sequence of Li+ + Na+-->K+ + Na+-->Rb+ + Na+-->Cs+ + Na+ corresponds to a product sequence of omega (+ analcime)-->offretite-->offretite-->analcime. With the new synthesis system, crystalline microporous materials including omega, offretite, analcime, and ferrierite can be readily obtained. The behaviors of the new synthesis system are discussed and compared with those of the normal hydrothermal synthesis system for zeolites. (C) 1997 Elsevier Science B.V.en
heal.journalNameMicroporous Materialsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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