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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Dokorou, V. | en |
| dc.contributor.author | Demertzis, M. A. | en |
| dc.contributor.author | Jasinski, J. P. | en |
| dc.contributor.author | Kovala-Demertzi, D. | en |
| dc.date.accessioned | 2015-11-24T16:49:06Z | - |
| dc.date.available | 2015-11-24T16:49:06Z | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9429 | - |
| dc.rights | Default Licence | - |
| dc.subject | 2-[bis(2,6-dimethylphenyl)amino]benzoic acid | en |
| dc.subject | diorganotin adducts | en |
| dc.subject | crystal structures | en |
| dc.subject | spectroscopic studies | en |
| dc.subject | palladium(ii) complexes | en |
| dc.subject | organotin complex | en |
| dc.subject | adducts | en |
| dc.subject | carboxylates | en |
| dc.subject | chemistry | en |
| dc.subject | tin(iv) | en |
| dc.title | Synthesis and spectroscopic studies of diorganotin derivatives with 2-[(2,6-dimethylphenyl)amino]benzoic acid. Crystal and molecular structure of the first complexes of 2-[(2,6-dimethylphenyl)amino]benzoic acid. Crystal and molecular structures of 1,2 : 3,4-di-mu(2)-2-[(2,6-dimethylphenyl)amino]benzoato-O,O-1,3-bis-2-[(2,6-dimethylphenyl)amino]benzoato-O-1,2,4 : 2,3,4-di-mu(3)-oxo-tetrakis[di-butyltin(IV)] and bis-2-[(2,6-dimethylphenyl)amino]benzoato-di-n-butyltin(IV) | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | DOI 10.1016/j.jorganchem.2003.10.018 | - |
| heal.identifier.secondary | <Go to ISI>://000188598000007 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0022328X03011082/1-s2.0-S0022328X03011082-main.pdf?_tid=fefa35e548334c5e70ea94cb36064756&acdnat=1333028539_ba21dbb52e0381730a28fd773e44a3e4 | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2004 | - |
| heal.abstract | The complexes [Bu-2(DMPA)SnOSn(DMPA)BU2](2) (2) and [BU2Sn(DMPA)(2)] (3), where HDMPA is 2-[bis(2,6-dimethylphenyl)amino]benzoic acid, have been prepared and structurally characterized by means of, vibrational, ultra-violet, H-1 and C-13 NMR spectroscopies. The crystal structure of complexes 2 and 3 have been determined by X-ray crystallography. Three distannoxane rings are present to the dimeric tetraorganodistannoxane of planar ladder arrangement of 2. The structure is centro-symmetric and features a central rhombus Sn2O2 unit with two additional tin atoms linked at the O atoms. Five- and six-coordinated tin centers are present in the dimmer distannoxane. The crystal structure of 3 consists of discrete molecular units and the two modeprononated ligands are co-ordinated to the SnBu2 fragment. The ligands act as anisobidentate chelating agents, thus rendering the tin atom sixco-ordinated. Significant pi-->pi, C-H-pi stacking interactions and intramolecular hydrogen bonds stabilize the structures 2 and 3. The polar imino hydrogen atom participates in intramolecular hydrogen bonds. Complexes 2 and 3 are self-assembled via pi-->pi, C-H-pi and stacking interactions. (C) 2003 Elsevier B.V. All rights reserved. | en |
| heal.journalName | Journal of Organometallic Chemistry | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Dokorou-2004-Synthesis and spectr.pdf | 438.56 kB | Adobe PDF | View/Open Request a copy |
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