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dc.contributor.authorKabanos, T. A.en
dc.contributor.authorWoollins, J. D.en
dc.date.accessioned2015-11-24T16:48:56Z-
dc.date.available2015-11-24T16:48:56Z-
dc.identifier.issn0300-9246-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9398-
dc.rightsDefault Licence-
dc.subjectsulfur-nitrogen ligandsen
dc.subjecttransition-metal complexesen
dc.subjectcrystal-structureen
dc.subjectspectrumen
dc.titleSynthesis and Characterization of Neutral Tris(Bidentate) Vanadium(V) Complexes Containing N3s23- and Catecholate Ligandsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://A1991FM50400030-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1991-
heal.abstractThe preparation and characterisation of complexes of the type [V(N3S2)Cl2L] (L = 2,2'-bipyridyl, 1; or 1,10-phenanthroline, 2) and [V(N3S2)L(L')] [L' = catecholate (cat) or 3,5-di-tert-butylcatecholate (dtbc)] 3-6 is described. The new complexes have been characterised by microanalyses, V-51 NMR, IR and visible spectroscopy as well as electrochemistry. All the new complexes are air stable as solids. Complexes 3 and 4 have a one-electron reversible couple and an anodic peak, whereas the dtbc complexes 5 and 6 have two one-electron reversible redox couples. The V-51 NMR spectra of 1-6 are characteristic, in particular there is a large downfield shift on replacing cat by dtbc.en
heal.journalNameJournal of the Chemical Society-Dalton Transactionsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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