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dc.contributor.authorEvgenidou, E.en
dc.contributor.authorKonstantinou, I.en
dc.contributor.authorFytianos, K.en
dc.contributor.authorAlbanis, T.en
dc.date.accessioned2015-11-24T16:48:37Z-
dc.date.available2015-11-24T16:48:37Z-
dc.identifier.issn0304-3894-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9349-
dc.rightsDefault Licence-
dc.subjectdichlorvosen
dc.subjectdimethoateen
dc.subjectphotocatalysisen
dc.subjectdegradation productsen
dc.subjectaqueous tio2 suspensionsen
dc.subjectphotodegradation productsen
dc.subjectgas-chromatographyen
dc.subjectreaction pathwayen
dc.subjectdegradationen
dc.subjectwateren
dc.subjectoxidationen
dc.subjectdecompositionen
dc.subjectpesticidesen
dc.subjecttoxicityen
dc.titleStudy of the removal of dichlorvos and dimethoate in a titanium dioxide mediated photocatalytic process through the examination of intermediates and the reaction mechanismen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.jhazmat.2006.03.042-
heal.identifier.secondary<Go to ISI>://000241135200046-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0304389406002822/1-s2.0-S0304389406002822-main.pdf?_tid=9cf0c1e61e419676221e9288226d2912&acdnat=1333022795_1b82fe1ce34eb688e5f3af785780f377-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2006-
heal.abstractThe photocatalytic oxidation of two selected organophosphorous insecticides (dichlorvos and dimethoate) has been investigated. The aim of the study was the identification of the intermediates that are formed during photocatalytic treatment. Intermediate products from the slurry system were identified by means of solid-phase extraction (SPE) coupled to gas chromatography-mass spectroscopy techniques (GC-MS). Nine possible by-products were identified for dimethoate and three for dichlorvos. A proposed degradation pathway for each insecticide is presented, involving mainly oxidation and dealkylation reactions. The results demonstrated that some of the transient intermediates formed (oxon derivatives, disulfide, chlorinated fragments), were more toxic compared to parent compounds whereas most of them are less toxic than the parent compounds. (c) 2006 Elsevier B.V. All rights reserved.en
heal.journalNameJ Hazard Materen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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