Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/9322
Full metadata record
DC FieldValueLanguage
dc.contributor.authorMylonas, M.en
dc.contributor.authorPlakatouras, J. C.en
dc.contributor.authorHadjiliadis, N.en
dc.contributor.authorPapavasilelou, K. D.en
dc.contributor.authorMelissas, V. S.en
dc.date.accessioned2015-11-24T16:48:26Z-
dc.date.available2015-11-24T16:48:26Z-
dc.identifier.issn0162-0134-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9322-
dc.rightsDefault Licence-
dc.subjecthistoriesen
dc.subjectpeptide modelsen
dc.subjectmetal complexesen
dc.subjectdft calculationsen
dc.subjectmolecular-orbital methodsen
dc.subjectgaussian-type basisen
dc.subjectmetal-binding siteen
dc.subjectorganic-moleculesen
dc.subjectoxidative damageen
dc.subjectserum-albuminen
dc.subjectsequenceen
dc.subjectnickel(ii)en
dc.subjectdensityen
dc.subjectcopper(ii)en
dc.titleAn extremely stable Ni(II) complex derived from the hydrolytic cleavage of the C-terminal tail of histone H2Aen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.jinorgbio.2004.11.020-
heal.identifier.secondary<Go to ISI>://000226392400033-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0162013404003824/1-s2.0-S0162013404003824-main.pdf?_tid=a56e2f46f95b483b4e80c23dbc971b71&acdnat=1333035951_bb12a3f97099ff54afbc3d9c0027d727-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2005-
heal.abstractThe C-terminal blocked tetrapeptides SHHK- and SAHK-, which represent the fragments produced from the hydrolysis of the hexapeptides' -TASHHK-, -TESHHK-, and -TESAHK- complexes with Ni(II), were synthesized and their interactions with Ni(II) ions were studied potentiometrically and spectroscopically. Both tetrapeptides interact strongly with Ni(II) ions leading to square-planar complexes with 4N {NH2,2N(-),N-im} coordination. The stability of the Ni-SHHK- complex is about 2 orders of magnitude higher than the Ni-SAHK- complex. Spectroscopic evidence and theoretical predictions suggest the positioning of the free imidazole ring, in the Ni-SHHK- complex, above the coordination plane, explaining the extra stability of the complex. (C) 2004 Elsevier Inc. All rights reserved.en
heal.publisherElsevieren
heal.journalNameJ Inorg Biochemen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

Files in This Item:
File Description SizeFormat 
Plakatouras-2005-An extremely stable Ni.pdf182.36 kBAdobe PDFView/Open    Request a copy


This item is licensed under a Creative Commons License Creative Commons