Please use this identifier to cite or link to this item:
https://olympias.lib.uoi.gr/jspui/handle/123456789/9282Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Parigoridi, I. E. | en |
| dc.contributor.author | Corban, G. J. | en |
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.contributor.author | Kourkoumelis, N. | en |
| dc.contributor.author | Kostakis, G. | en |
| dc.contributor.author | Psycharis, V. | en |
| dc.contributor.author | Raptopoulou, C. P. | en |
| dc.contributor.author | Kubicki, M. | en |
| dc.date.accessioned | 2015-11-24T16:48:07Z | - |
| dc.date.available | 2015-11-24T16:48:07Z | - |
| dc.identifier.issn | 1477-9226 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9282 | - |
| dc.rights | Default Licence | - |
| dc.subject | x-ray characterization | en |
| dc.subject | charge-transfer complexes | en |
| dc.subject | antithyroid drugs | en |
| dc.subject | iodothyronine deiodinase | en |
| dc.subject | heterocyclic thioamides | en |
| dc.subject | crystal-structure | en |
| dc.subject | transfer adducts | en |
| dc.subject | oxidation | en |
| dc.subject | iodine | en |
| dc.subject | mechanism | en |
| dc.title | Structural motifs of diiodine complexes with amides and thioamides | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | Doi 10.1039/B805825c | - |
| heal.identifier.secondary | <Go to ISI>://000259411500008 | - |
| heal.identifier.secondary | http://pubs.rsc.org/en/content/articlepdf/2008/dt/b805825c | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2008 | - |
| heal.abstract | The reaction of 2-pyrimidone hydrochloride ([C(4)H(5)N(2)O](+)[Cl](-) or [PMOH(2)](+)[Cl](-)) with diiodine in a dichloromethane-methanol solution resulted in the formation of ([C(4)H(5)N(2)O](+))(2)[I(2)Cl(2)](2-) (1) complex. The compound was characterized by elemental analysis, FT-IR, DTA-TG and conductivity titrations. The crystal structure of 1 was also determined by X-ray diffraction at 294(1) K. Compound 1 is monoclinic, space group P2(1)/n, consisting of two cationic [PMOH(2)](+) species and a [I(2)Cl(2)](2-) counter dianion. The cation is in its keto form. Direct reaction of thiazolidine-2-thione (tzdtH), with diiodine in dichloromethane solution, on the other hand, led to the formation of a crystalline solid which contained two complexes of formulae [(tzdtH)(2)I](+)[I(3)](-)center dot 2I(2) (2) and [(tzdtH)I(2)](2)center dot I(2) (2a) in a ratio of 90 to 10%. Complex 2a was characterized by X-ray analysis at 180(2) K. Compound 2a is monoclinic, space group C2/c and contains two units of [(tzdtH)I(2)] "spoke" structures. Compound 1, as well as the known species iodonium salt [(tzdtH)(2)I](+)[I(3)](-)center dot 2I(2) (2) and the charge transfer (CT) iodine complexes of formulae [(bztzdtH)I(2)] (3) and [(bztzdtH)I(2)]center dot I(2) (4) (bztzdtH = 2-mercaptobenzothiazole) with "spoke" and extended "spoke" structures respectively, were tested for their oxidizing activity towards 3,5-di-tert-butylcatechol to 3,5-di-tert-butyl-o-benzoquinone. | en |
| heal.publisher | Royal Society of Chemistry | en |
| heal.journalName | Dalton Transactions | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Parigoridi-2008-Structural motifs of.pdf | 223.61 kB | Adobe PDF | View/Open Request a copy |
This item is licensed under a Creative Commons License
