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dc.contributor.authorStergiou, D. V.en
dc.contributor.authorStergiopoulos, T.en
dc.contributor.authorFalaras, P.en
dc.contributor.authorProdromidis, M. I.en
dc.date.accessioned2015-11-24T16:47:29Z-
dc.date.available2015-11-24T16:47:29Z-
dc.identifier.issn1388-2481-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9191-
dc.rightsDefault Licence-
dc.subjecton-line monitoring of ozoneen
dc.subjectsolid redox polymer electrolytesen
dc.subjectpolyethylene oxideen
dc.subjectiodide/iodineen
dc.subjectelectrochemical sensorsen
dc.subjectfilmsen
dc.subjectcellsen
dc.titleSolid redox polymer electrolyte-based amperometric sensors for the direct monitoring of ozone in gas phaseen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.elecom.2009.09.007-
heal.identifier.secondary<Go to ISI>://000272115600010-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1388248109004445/1-s2.0-S1388248109004445-main.pdf?_tid=e30a4f8d7a104947f6dd085db2ebdf0a&acdnat=1333037403_177d2a0def148e6c0dcd892436817f01-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2009-
heal.abstractThe response of solid redox polymer electrolytes of the type polyethylene oxide (PEO)XI/I(2) (X: Li, Rb) towards O(3) in gas phase is reported for the first time. The proposed approach is based on the current recorded at a redox polymer electrolyte-modified two-gold-surface electrode assembly poised at +300 mV. Ozone reacts with the iodide species in the bulk electrolyte producing triiodides. This results in the increase of the diffusion rate of I(3)(-) to the cathode where I(3)(-) are reduced to iodides, giving thus rise to the production of a faradic response. Various experimental parameters were optimized and the best results were obtained for the PEO/RbI/I(2) redox polymer, which is successfully used for the on-line monitoring of O(3) in synthetic air samples in ambient conditions. (C) 2009 Elsevier B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameElectrochemistry Communicationsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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