Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/9161
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dc.contributor.authorCox, P. J.en
dc.contributor.authorAslanidis, P.en
dc.contributor.authorKaragiannidis, P.en
dc.contributor.authorHadjikakou, S.en
dc.date.accessioned2015-11-24T16:47:17Z-
dc.date.available2015-11-24T16:47:17Z-
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9161-
dc.rightsDefault Licence-
dc.subjectcrystal structuresen
dc.subjectheterocyclic thione complexesen
dc.subjectphotolysisen
dc.subjectsilver(i) bromide complexesen
dc.subjecttriphenylphosphine complexesen
dc.subjectcopper(i) bromideen
dc.subjectcu(i) complexesen
dc.subjectmononuclearen
dc.subjecttriphenylphosphineen
dc.titleSilver(I) complexes with heterocyclic thiones and tertiary phosphines as ligands. Part 4. Dinuclear complexes of silver(I) bromide: the crystal structure of bis[bromo-(pyrimidine-2-thione)(triphenylphosphine)silver(I)]en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primary10.1016/S0020-1693(00)00286-3-
heal.identifier.secondary<Go to ISI>://000166250900023-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169300002863/1-s2.0-S0020169300002863-main.pdf?_tid=7fbbbed56a3dc4d82b55bb330f6e4146&acdnat=1333030103_e2eacadf42ab093500d41e6018cf77b1-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2000-
heal.abstractMixed-ligand complexes of the formula [Ag(PPh3)(L)Br](2) were obtained by treatment of various heterocyclic thiones L (L = pyridine-2-thione (py2SH), pyrimidine-2-thione (pymtH), bent-1,3-imidazoline-2-thione (bzimtH(2)), benz-1,3-thiazoline-2-thione (bztztH). 1-methyl-1,3-imidazoline-2-thione (meimtH) and 5-methoxy-benz-1,3-imidazoline-2-thione (5MeObzimtH(2))) with equivalent quantities of silver(I) bromide and triphenylphosphine in dry acetone. The compounds were characterized by their IR, far-IR, UV-Vis and H-1 NMR spectroscopic data. The crystal structure of [Ag(PPh3)(pymtH)Br](2) was determined by single-crystal X-ray diffraction methods. The complex exhibits a planar Ag2Br2 moiety in which each of the doubly bromine-bridged Ag(I) centres is further bonded to one phosphine P and one thione S atom. (C) 2000 Elsevier Science B.V. All rights reserved.en
heal.publisherElsevieren
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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