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dc.contributor.authorKatranas, T. K.en
dc.contributor.authorTriantafyllidis, K. S.en
dc.contributor.authorVlessidis, A. G.en
dc.contributor.authorEvmiridis, N. P.en
dc.date.accessioned2015-11-24T16:45:36Z-
dc.date.available2015-11-24T16:45:36Z-
dc.identifier.issn1011-372X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8957-
dc.rightsDefault Licence-
dc.subjectpropaneen
dc.subjectcatalysisen
dc.subjectdehydrogenationen
dc.subjectcrackingen
dc.subjectzeolites type-x and usyen
dc.subjectpromoted h-zsm-5 catalystsen
dc.subjectring co-zeolitesen
dc.subjectoxidative dehydrogenationen
dc.subjectptsn/zsm-5 catalysten
dc.subjectsolid acidsen
dc.subjectaromatizationen
dc.subjectperformanceen
dc.subjectconversionen
dc.subjectaromaticsen
dc.subjectgalliumen
dc.titlePropane reactions over faujasite structure zeolites type-X and USY: Effect of zeolite silica over alumina ratio, strength of acidity and kind of exchanged metal ionen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1007/s10562-007-9152-3-
heal.identifier.secondary<Go to ISI>://000249646200013-
heal.identifier.secondaryhttp://download.springer.com/static/pdf/94/art%253A10.1007%252Fs10562-007-9152-3.pdf?auth66=1381994683_ee27a811265d4fe42f302dfac83618c9&ext=.pdf-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2007-
heal.abstractIn this work we prepared various zeolite-X and USY samples partially exchanged with copper, iron and platinum. These samples were characterized by XRD, Chemical Analysis, SEM-EDS, N-2-adsorption-desorption, ammonia-TPD, and tested as catalysts in high temperature (400 and 550 degrees C) propane transformation. The obtained results revealed the strong effect of Si/Al ratio in faujasite zeolite structure, the number and strength of acid sites and of the presence of different metal ions in countered ion sites, on the catalytic activity and selectivity of zeolite-X and USY. The highest propane dehydrogenation activity was achieved with the platinum-exchanged X zeolite (similar to 11.2% propylene yield, similar to 31% selectivity). On the contrary USY zeolites showed high cracking capability and relatively low dehydrogenation activity excepting the platinum-exchanged sample which yielded notably high aromatization products.en
heal.publisherSpringer Verlag (Germany)en
heal.journalNameCatalysis Lettersen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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