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dc.contributor.authorSkordilis, C. S.en
dc.contributor.authorPomonis, P. J.en
dc.date.accessioned2015-11-24T16:45:25Z-
dc.date.available2015-11-24T16:45:25Z-
dc.identifier.issn0021-9797-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8929-
dc.rightsDefault Licence-
dc.subjectultrafine particlesen
dc.subjectmagnetic-propertiesen
dc.subjectcrystal-structuresen
dc.subjectcatalysten
dc.subjectaciden
dc.titlePreparation of Fine Manganese Oxidic Particles Via Hydrolysis of a Multinuclear Manganese Complexen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://A1994NX81500009-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0021979784712719/1-s2.0-S0021979784712719-main.pdf?_tid=b7e80b6f07a375fcd511bf66a16a3adf&acdnat=1333036785_134e0d5c8628f56e0d683c8fec3e459d-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1994-
heal.abstractFine manganese oxidic species have been prepared by hydrolysis of a trinuclear manganese complex [Mn3O (CH3COO)6(pyr)3]ClO4. The obtained particles possess a high BET-specific surface area 150-200 m2 g-1 between 200 and 400-degrees-C, which drops to 50 m2 g-1 at 500-degrees-C. TG studies showed that the dried material (110-degrees-C) loses approximately 10% of its weight between 100 and 200-degrees-C. Thereafter and between 200 and 500-degrees-C, a constant rate of weight loss appears, totaling around 3.5%. The material appears amorphous in XRD in the high-surface-area region (T < 400-degrees-C) and crystalline thereafter. Adsorption-desorption of N2 at T = 77 K showed a hysteresis loop, characteristic of mesoporous solids. SEM photographs indicated the existence of particles of size 0.1-0.2 mum. (C) 1994 Academic Press, Inc.en
heal.publisherAcademic Pressen
heal.journalNameJ Colloid Interface Scien
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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