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dc.contributor.authorAkrivos, P. D.en
dc.contributor.authorKapsomenos, G.en
dc.contributor.authorKaragiannidis, P.en
dc.contributor.authorSkoulika, S.en
dc.contributor.authorAubry, A.en
dc.date.accessioned2015-11-24T16:45:23Z-
dc.date.available2015-11-24T16:45:23Z-
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8924-
dc.rightsDefault Licence-
dc.subjectcu(i) complexesen
dc.subjectheterocyclic thionesen
dc.subjecttolylphosphineen
dc.subjectphotolysisen
dc.subjectmodelsen
dc.subjectseriesen
dc.titlePreparation and Study of 3-Coordinate Mixed-Ligand Copper(I) Compounds - Molecular and Crystal-Structure of (Tricyclohexylphosphine)(2-Thioxohexamethyleneimine)Copper(I) Iodideen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://A1992KC62600013-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169300853530/1-s2.0-S0020169300853530-main.pdf?_tid=df7f80e75c4164e02be6c9a4343f8327&acdnat=1333040501_2e5a6c78d20f0ed0b90f72c61dda4f2d-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate1992-
heal.abstractA group of mixed ligand copper(I) coordination compounds with the saturated heterocyclic thione 2-thioxohexamethyleneimine (omega-thiocaprolactam, tclH) and tricyclohexylphosphine (Pcy3) is prepared and studied. The concerted steric effects of the two bulky ligands result in the formation of three-coordinate copper(I) complexes. The iodo compound is studied by single crystal X-ray diffraction and is shown to crystallize in the P2(1)/n space group. Four monomer units with no apparent close contacts between them are present in the unit cell, the dimensions of which are a = 10.306(2), b = 15.937(2), c = 16.774(2) angstrom, and beta = 100.06(1)-degrees. The compound is trigonal planar with the Cu-S, Cu-P and Cu-I bonds equal to 2.243(2), 2.241(2) and 2.564(1) angstrom respectively. A computational study is also carried out aiming at the understanding of the factors influencing planar or pyramidal conformation in three-coordinate CuLL'L" compounds.en
heal.publisherElsevieren
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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