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dc.contributor.authorAslanidis, P.en
dc.contributor.authorHadjikakou, S. K.en
dc.contributor.authorKaragiannidis, P.en
dc.contributor.authorKojic-Prodic, B.en
dc.contributor.authorLuic, M.en
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dc.titlePreparation and spectral studies of dinuclearmixed-ligand copper(I) complexes. The crystal structure of bis[ΞΌ-S(Pyridine-2-Thione)(tmtp) Copper(I)Bromide]en
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.abstract[Cu(tmtp)Br]n (tmtp = tri-m-tolylphosphine) reacts with heterocyclic thiones (L) [L = pyridine-2-thione (py2SH), 1,3-thiazolidine-2-thione (tzdtH), benz-1,3-imidazoline-2-thione (bzimtH2), benz-1,3-thiazoline-2-thione (bztzdtH), imidazoline-2-thione (imtH), benz-1,3-oxazoline-2-thione (bzoxtH2), 5-nitrobenz-1,3-imidazoline-2-thione (nbzimtH2), and 5-methyl-benz-1,3-imidazoline-2-thione (mebzimtH2)] to give binuclear complexes of the general formula [Cu(tmtp)(L)Br]2. These complexes have been characterized by various spectroscopic methods. The crystal structure of the pyridine-2-thione complex has been determined by single-crystal X-ray diffraction methods. The molecule contains a planar Cu2S2 moiety with Cuξ—ΈS bond lengths of 2.3348(9) and 2.4879(7) Γ…. The Cuξ—ΈBr and Cuξ—ΈP distances are 2.4929(1) and 2.2525(4) Γ…, respectively, whereas the Cuβ‹―Cu separation is 2.6906(1) Γ….en
heal.journalTypepeer reviewed-
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