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https://olympias.lib.uoi.gr/jspui/handle/123456789/8758Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Demertzis, M. A. | en |
| dc.contributor.author | Yadav, P. N. | en |
| dc.contributor.author | Kovala-Demertzi, D. | en |
| dc.date.accessioned | 2015-11-24T16:43:58Z | - |
| dc.date.available | 2015-11-24T16:43:58Z | - |
| dc.identifier.issn | 0018-019X | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8758 | - |
| dc.rights | Default Licence | - |
| dc.subject | vivo antitumor-activity | en |
| dc.subject | 2-acetyl pyridine | en |
| dc.subject | platinum(ii) complexes | en |
| dc.subject | spectral properties | en |
| dc.subject | cytotoxic activity | en |
| dc.subject | derivatives | en |
| dc.subject | reductase | en |
| dc.subject | agents | en |
| dc.subject | pd(ii) | en |
| dc.subject | DNA | en |
| dc.title | Palladium(II) complexes of the thiosemicarbazone and N-ethylthiosemicarbazone of 3-hydroxypyridine-2-carbaldehyde: Synthesis, properties, and X-ray crystal structure | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | <Go to ISI>://000241200200012 | - |
| heal.identifier.secondary | http://onlinelibrary.wiley.com/store/10.1002/hlca.200690187/asset/1959_ftp.pdf?v=1&t=h0dulejs&s=31dd3decd2156d962e5c141ccd7511c42f7e2a7f | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2006 | - |
| heal.abstract | Two novel, stable Pd-II complexes, compounds 3 and 4, of two 3-hydroxypyridine-2-carbaldehyde thiosemicarbazones, 1 and 2, resp., were prepared from Li2PdCl4. The single-crystal X-ray structure of complex 3 (=[Pd(2)Cl]) shows that the ligand monoanion coordinates in a planar conformation to the metal via the pyridyl N-, the imine N-, and the thiolato S-atoms. Intermolecular H-bonds, pi-pi, and CH...pi interactions lead to a two-dimensional supramolecular assembly. The electronic, IR, UV/VIS, and NMR spectroscopic data of the two complexes are reported, together with their electrochemical properties. A sophisticated experimental procedure was used to determine the multiple dissociation constants of the ligands 1 and 2 by UV/VIS titration. | en |
| heal.journalName | Helvetica Chimica Acta | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Demertzis-2006-Palladium(II) comple.pdf | 318.42 kB | Adobe PDF | View/Open Request a copy |
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