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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/8750
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dc.contributor.authorPapathanasis, L.en
dc.contributor.authorDemertzis, M. A.en
dc.contributor.authorYadav, P. N.en
dc.contributor.authorKovala-Demertzi, D.en
dc.contributor.authorPrentjas, C.en
dc.contributor.authorCastineiras, A.en
dc.contributor.authorSkoulika, S.en
dc.contributor.authorWest, D. X.en
dc.date.accessioned2015-11-24T16:43:53Z-
dc.date.available2015-11-24T16:43:53Z-
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8750-
dc.rightsDefault Licence-
dc.subjectpalladium(ii)en
dc.subjectplatinum(ii)en
dc.subjectthiosemicarbazoneen
dc.subjectcrystal structuresen
dc.subjectspectroscopyen
dc.subjectprotonation constantsen
dc.subject2-hydroxyacetophenone n-4-substituted thiosemicarbazonesen
dc.subjectcopper(ii) complexesen
dc.subjecttripalladium complexen
dc.subjectligandsen
dc.subjectadductsen
dc.titlePalladium(II) and platinum(II) complexes of 2-hydroxy acetophenone N(4)-ethylthiosemicarbazone - crystal structure and description of bonding propertiesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.ica.2004.06.048-
heal.identifier.secondary<Go to ISI>://000225452100008-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169304003202/1-s2.0-S0020169304003202-main.pdf?_tid=4f96ef7702e2033eb93afc8c8d474399&acdnat=1333028884_a18eacc865e13209876a7e31c5952020-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2004-
heal.abstractReaction of H2PtCl4 and K2PdCl4 with 2-hydroxyacetophenone N(4)-ethylthiosenticarbazone, H(2)Ap4Et, afforded [Pt(Ap4Et)(H(2)Ap4Et)] and [Pd(Ap4Et)(H(2)Ap4Et)]. Their crystal and molecular structures are reported and represent the first 1:2 thiosemicarbazone complexes with ligands having both different formal charge and denticity. The dianion, Ap4Et(2-), coordinates in a planar conformation to palladium(II) or platinum(II) via the phenolato 0, imine N and thiolato S atoms, while the neutral molecule exhibits monodentate coordination by the thione S atom. Intra-, intermolecular hydrogen bonds and C-H... pi contacts lead to aggregation and a supramolecular assembly. Electronic, IR, and NMR spectral data, as well as electrochemical measurements, are included. The pK(a) values of the poorly water soluble H2Ap4Et were obtained spectrophotometrically in aqueous solutions of constant ionic strength. (C) 2004 Elsevier B.V. All rights reserved.en
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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