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DC Field | Value | Language |
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dc.contributor.author | Wiecek, J. | en |
dc.contributor.author | Kovala-Demertzi, D. | en |
dc.contributor.author | Ciunik, Z. | en |
dc.contributor.author | Wietrzyk, J. | en |
dc.contributor.author | Zervou, M. | en |
dc.contributor.author | Demertzis, M. A. | en |
dc.date.accessioned | 2015-11-24T16:43:35Z | - |
dc.date.available | 2015-11-24T16:43:35Z | - |
dc.identifier.issn | 1565-3633 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8717 | - |
dc.rights | Default Licence | - |
dc.subject | palladium(ii) complexes | en |
dc.subject | 2-acetyl pyridine | en |
dc.subject | diorganotin derivatives | en |
dc.subject | platinum(ii) complexes | en |
dc.subject | molecular-structures | en |
dc.subject | spectral properties | en |
dc.subject | drug interactions | en |
dc.subject | metal-complexes | en |
dc.subject | 1st complexes | en |
dc.subject | thiosemicarbazone | en |
dc.title | Organotin Compound Derived from 3-Hydroxy-2-formylpyridine Semicarbazone: Synthesis, Crystal Structure, and Antiproliferative Activity | en |
heal.type | journalArticle | - |
heal.type.en | Journal article | en |
heal.type.el | Άρθρο Περιοδικού | el |
heal.identifier.primary | Doi 10.1155/2010/718606 | - |
heal.identifier.secondary | <Go to ISI>://000278144700001 | - |
heal.identifier.secondary | http://downloads.hindawi.com/journals/bca/2010/718606.pdf | - |
heal.language | en | - |
heal.access | campus | - |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.publicationDate | 2010 | - |
heal.abstract | The novel diphenyltin(IV) compound [Ph(2)(HyFoSc)Sn] (2), where H(2)HyFoSc (1) is 3-hydroxy-2-formylpyridine semicarbazone, was prepared and characterized by vibrational and NMR ((1)H, (13)C) spectroscopy. The structure of [Ph(2)(HyFoSc)Sn] was confirmed by single-crystal X-ray crystallography. The doubly deprotonated ligand is coordinated to the tin atom through the enolic-oxygen, the azomethine-nitrogen, and phenolic-oxygen, and so acts as an anionic tridentate ligand with the ONO donors. Two carbon atoms complete the fivefold coordination at the tin( IV) center. Intermolecular hydrogen bonding, C-H -> pi, and pi -> pi interactions combine to stabilize the crystal structure. Compounds 1 and 2 have been evaluated for antiproliferative activity in vitro against the cells of three human tumor cell lines: MCF-7 (human breast cancer cell line), T24 (bladder cancer cell line), A549 (nonsmall cell lung carcinoma), and a mouse fibroblast L-929 cancer cell line. | en |
heal.journalName | Bioinorg Chem Appl | en |
heal.journalType | peer reviewed | - |
heal.fullTextAvailability | TRUE | - |
Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ |
Files in This Item:
File | Description | Size | Format | |
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Wiecek-2010-Organotin Compound D.pdf | 1.22 MB | Adobe PDF | View/Open |
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