Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/8535
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dc.contributor.authorKontos, A. G.en
dc.contributor.authorFardis, M.en
dc.contributor.authorProdromidis, M. I.en
dc.contributor.authorStergiopoulos, T.en
dc.contributor.authorChatzivasilogiou, E.en
dc.contributor.authorPapavassiliou, G.en
dc.contributor.authorFalaras, P.en
dc.date.accessioned2015-11-24T16:42:20Z-
dc.date.available2015-11-24T16:42:20Z-
dc.identifier.issn1463-9076-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8535-
dc.rightsDefault Licence-
dc.subjectnuclear-magnetic-resonanceen
dc.subjectsensitized solar-cellsen
dc.subjectcolloidal tio2 filmsen
dc.subjectsolid-stateen
dc.subjectphotoelectrochemical cellsen
dc.subjectself-diffusionen
dc.subjectconversion efficienciesen
dc.subjectlithiumen
dc.subjectbatteriesen
dc.subjecttransporten
dc.titleMorphology, ionic diffusion and applicability of novel polymer gel electrolytes with LiI/I(2)en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1039/B515113a-
heal.identifier.secondary<Go to ISI>://000235608500012-
heal.identifier.secondaryhttp://pubs.rsc.org/en/content/articlepdf/2006/cp/b515113a-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2006-
heal.abstractNovel polymer gel electrolytes have been prepared by incorporating LiI-I(2) solutions into a polyethylene oxide matrix supported by a TiO(2) filler. The gel electrolytes, based on either acetonitrile or propylene carbonate solvents are compared with liquid standard ones and are examined by (7)Li solid state nuclear magnetic resonance relaxometry and diffusion measurements. In parallel, the triiodide apparent diffusion coefficient has been determined by linear sweep voltammetry. The results are correlated with atomic force microscopic images of the electrolytes and give insight of the dynamic properties of the ions in the constrained polymer medium. Furthermore, the dissociation of the ions is estimated by relating the ionic conductivity to the ionic diffusion. As a prime application, the polymer gel electrolytes were incorporated in dye sensitized solar cells and the measured energy conversion efficiencies were successfully correlated with their morphological, diffusive and conducting properties.en
heal.publisherThe Royal Society of Chemistryen
heal.journalNamePhysical Chemistry Chemical Physicsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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