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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Garoufis, A. | en |
| dc.contributor.author | Koutsodimou, A. | en |
| dc.contributor.author | Katsaros, N. | en |
| dc.contributor.author | Mitsopoulou, C. A. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.date.accessioned | 2015-11-24T16:41:55Z | - |
| dc.date.available | 2015-11-24T16:41:55Z | - |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8489 | - |
| dc.rights | Default Licence | - |
| dc.subject | 2-(2 '-pyridyl)quinoxaline | en |
| dc.subject | ru(ii) complexes | en |
| dc.subject | electrospray-ms | en |
| dc.subject | 2,2 '-bipyridine | en |
| dc.subject | ruthenium(ii) complexes | en |
| dc.subject | excited-states | en |
| dc.subject | polypyridine complexes | en |
| dc.subject | electrochemistry | en |
| dc.subject | spectroscopy | en |
| dc.subject | 1,10-phenanthroline | en |
| dc.subject | photochemistry | en |
| dc.subject | photophysics | en |
| dc.subject | binding | en |
| dc.subject | metal | en |
| dc.title | Mixed ligand Ru(II) complexes with 2,2 '-bipyridine and 2-(2 '-pyridyl)quinoxaline | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | <Go to ISI>://000078033700007 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538798003040/1-s2.0-S0277538798003040-main.pdf?_tid=2d09b6835eefb436f6a8c681baeb4f88&acdnat=1333029202_8585353be1f0269d49f409f1d21c4eac | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 1999 | - |
| heal.abstract | The synthesis and the physical properties of a new series of Ru(II) mixed ligand tris chelate complexes of the type [LxRu(bpy)(3-x)], where L = 2-(2'-pyridyl) quinoxaline and bpy = 2,2'-bipyridine, are reported. The complexes were fully characterized by NMR spectroscopic techniques, Electrospray Mass Spectroscopy, UV-visible spectra and elemental analyses. The complex [RuL3](PF6)(2) probably has the mer conformation due to the bulky shape of the L on the side of quinoxaline. The complex [RuL2(bpy)](PF6)(2) was isolated as a mixture of all three possible geometric isomers, while the [RuL(bpy)(2)](PF6)(2) in only one isomer as theoretically expected. Photoinduced dissociation of one molecule of the ligand L from the complex [RuL3](PF6)(2) upon exposure to room light has been studied by H-1 NMR and UV-vis Spectroscopies. (C) 1998 Elsevier Science Ltd. All rights reserved. | en |
| heal.publisher | Elsevier | en |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Garoufis-1999-Mixed ligand Ru(II).pdf | 313.62 kB | Adobe PDF | View/Open Request a copy |
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