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dc.contributor.authorDimou, A. D.en
dc.contributor.authorSakkas, V. A.en
dc.contributor.authorAlbanis, T. A.en
dc.date.accessioned2015-11-24T16:41:38Z-
dc.date.available2015-11-24T16:41:38Z-
dc.identifier.issn0021-8561-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8449-
dc.rightsDefault Licence-
dc.subjectphotodegradationen
dc.subjectmetolachloren
dc.subjectdissolved organic matteren
dc.subjectfateen
dc.subjectherbicide metolachloren
dc.subjectdegradation-productsen
dc.subjectbacterial communityen
dc.subjectsoilen
dc.subjectwateren
dc.subjectpesticidesen
dc.subjecttransformationen
dc.subjectmetabolismen
dc.subjectphotolysisen
dc.subjectalachloren
dc.titleMetolachlor photodegradation study in aqueous media under natural and simulated solar irradiationen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Jf048766-
heal.identifier.secondary<Go to ISI>://000226782900031-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdf/10.1021/jf048766w-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2005-
heal.abstractTo elucidate the photochemical behavior of pesticide metolachlor, degradation was carried out in aqueous media of different compositions such as sea, river, lake, and distilled water under natural and simulated solar irradiation. In addition, the effect of important constituents of natural water such as dissolved organic matter (DOM, isolated from Pamvotis Lake) and nitrate ions was also examined. It was found that photodegradation proceeds via a pseudo-first-order reaction in all cases. The presence of DOM inhibits the photolysis reaction with half-lives ranging from 87 to 693 In whereas the degradation rate was accelerated up to 11 times in the presence of NO3-. In addition, the toxicity of the degradation products formed (generally through hydroxylation, dealkylation, and cyclization reactions) was also performed using the marine luminescent bacterium Vibrio fisheri. Our results indicated a toxicity increase of the irradiated solution showing that photoproducts of higher acute toxic effects were formed.en
heal.publisherAmerican Chemical Societyen
heal.journalNameJ Agric Food Chemen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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