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DC Field | Value | Language |
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dc.contributor.author | Christoforidis, K. C. | en |
dc.contributor.author | Serestatidou, E. | en |
dc.contributor.author | Louloudi, M. | en |
dc.contributor.author | Konstantinou, I. K. | en |
dc.contributor.author | Milaeva, E. R. | en |
dc.contributor.author | Deligiannakis, Y. | en |
dc.date.accessioned | 2015-11-24T16:41:24Z | - |
dc.date.available | 2015-11-24T16:41:24Z | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8414 | - |
dc.rights | Default Licence | - |
dc.subject | chlorophenol | en |
dc.subject | tcp | en |
dc.subject | dcq | en |
dc.subject | radical | en |
dc.subject | epr | en |
dc.subject | lc-ms | en |
dc.subject | oxidation products | en |
dc.subject | dehalogenation | en |
dc.subject | heme catalyst | en |
dc.subject | heterogeneous catalyst | en |
dc.subject | catalytic mechanism | en |
dc.subject | water-soluble iron(iii) | en |
dc.subject | oxidative-degradation | en |
dc.subject | chlorinated phenols | en |
dc.subject | iron tetrasulfophthalocyanine | en |
dc.subject | h2o2 oxidation | en |
dc.subject | complex | en |
dc.subject | pentachlorophenol | en |
dc.subject | chlorophenols | en |
dc.subject | dechlorination | en |
dc.subject | dehalogenation | en |
dc.title | Mechanism of catalytic degradation of 2,4,6-trichlorophenol by a Fe-porphyrin catalyst | en |
heal.type | journalArticle | - |
heal.type.en | Journal article | en |
heal.type.el | Άρθρο Περιοδικού | el |
heal.identifier.primary | DOI 10.1016/j.apcatb.2010.10.011 | - |
heal.identifier.secondary | <Go to ISI>://000287068400030 | - |
heal.identifier.secondary | http://ac.els-cdn.com/S0926337310004583/1-s2.0-S0926337310004583-main.pdf?_tid=0d9fb526-362f-11e3-bcb3-00000aacb360&acdnat=1381906327_7fc66545c81fd942016af29740c1aecf | - |
heal.language | en | - |
heal.access | campus | - |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.publicationDate | 2011 | - |
heal.abstract | The catalytic oxidation of 2,4,6-trichlorophenol (TCP) by a homogeneous Fe-porphyrin catalyst (FeR(4)P) and the corresponding heterogeneous one (immobilized on silica, FeR(4)P-SiO(2)) was studied by analytical and EPR spectroscopic methods. The homogeneous catalyst was found to be more efficient for oxidative decomposition and dechlorination of TCP, compared to the heterogeneous FeR(4)P-SiO(2) catalyst. The main, initial and final, oxidation products were identified and a general catalytic mechanism was proposed concerning TCP oxidation and the by-products formation, in relation with the catalyst's redox cycle. (C) 2010 Elsevier B.V. All rights reserved. | en |
heal.publisher | Elsevier | en |
heal.journalName | Applied Catalysis B-Environmental | en |
heal.journalType | peer reviewed | - |
heal.fullTextAvailability | TRUE | - |
Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ |
Files in This Item:
File | Description | Size | Format | |
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Christoforidis-2011-Mechanism of catalyt.pdf | 367.66 kB | Adobe PDF | View/Open Request a copy |
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