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https://olympias.lib.uoi.gr/jspui/handle/123456789/8400Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Serafimidou, A. | en |
| dc.contributor.author | Stamatis, A. | en |
| dc.contributor.author | Louloudi, M. | en |
| dc.date.accessioned | 2015-11-24T16:41:18Z | - |
| dc.date.available | 2015-11-24T16:41:18Z | - |
| dc.identifier.issn | 1566-7367 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8400 | - |
| dc.rights | Default Licence | - |
| dc.subject | biomimetic catalytic epoxidation | en |
| dc.subject | supported manganese complexes | en |
| dc.subject | h2o2 activation | en |
| dc.subject | modified silica surface | en |
| dc.subject | hydrogen-peroxide | en |
| dc.subject | hydrocarbon oxygenations | en |
| dc.subject | oxidation | en |
| dc.subject | efficient | en |
| dc.subject | porphyrins | en |
| dc.subject | silica | en |
| dc.subject | cocatalyst | en |
| dc.title | Manganese(II) complexes of imidazole based-acetamide as homogeneous and heterogenised catalysts for alkene epoxidation with H2O2 | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | DOI 10.1016/j.catcom.2007.05.015 | - |
| heal.identifier.secondary | <Go to ISI>://000251573100007 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S1566736707002130/1-s2.0-S1566736707002130-main.pdf?_tid=ebad140e-362e-11e3-b42e-00000aab0f02&acdnat=1381906270_3e62d75aa7910f9ba015be56e62f7bcf | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2008 | - |
| heal.abstract | An acetamide derivative which bears two terminal imidazole rings has been synthesized. This biomimetic ligand, N-[2-(1 H-imidazol-4yl)-ethyl]-2-(1[2-(1H-imidazol-4-yl)-ethylcarbamoyl]-methyl)-amino)-acetamide, has been also grafted on silica surface via covalent bond. The supported and non-supported biomimetics reacted with manganese(II) ions leading to the formation of the corresponding metal complexes. These have been evaluated as catalysts for alkene epoxidation with H2O2 in the presence of ammonium acetate as an additive. Our data showed that the homogeneous and the supported systems are able to overcome the competitive H2O2 dismutation, by the use of only two times H2O2 with respect to substrate, favouring productive alkene epoxiclations to a significant extent. (c) 2007 Elsevier B.V. All rights reserved. | en |
| heal.publisher | Elsevier | en |
| heal.journalName | Catalysis Communications | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Serafimidou-2008-Manganese(II) comple.pdf | 129.64 kB | Adobe PDF | View/Open Request a copy |
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