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dc.contributor.authorElemes, Y.en
dc.contributor.authorMuir, K. W.en
dc.date.accessioned2015-11-24T16:39:11Z-
dc.date.available2015-11-24T16:39:11Z-
dc.identifier.issn0108-2701-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8127-
dc.rightsDefault Licence-
dc.subjecttriazolinedione ene reactionsen
dc.subjectsinglet oxygenen
dc.subjectstereochemistryen
dc.subjectnitrosoareneen
dc.subjectderivativesen
dc.subjectaciden
dc.titleHydrated forms of N-[(3R)-3-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-2-methylene-butanoyl]-(1S,2R)-bornane-10,2-sultam and its enantiomeren
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1107/S0108270106019524-
heal.identifier.secondary<Go to ISI>://000239485400024-
heal.identifier.secondaryhttp://journals.iucr.org/c/issues/2006/08/00/dn3017/dn3017.pdf-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2006-
heal.abstractTriazolidinediones react with each enantiomeric bornanesultam derivative of tiglic acid to produce the appropriate ene adduct in high yield and with excellent regioselectivity and diastereoselectivity. The optically pure products, viz. N-[(3R)-3-(4methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-2-methylenebutanoyl](1S,2R)-bornane-10,2-sultam 0.15-hydrate, C(18)H(26)N(4)O(5)S(.)0.35H(2)O, and its enantiomer N-[(3S)-3-(4-methyl-3,5-dioxo1,2,4-triazolidin-1-yl)-2-methylenebutanoyl]-(1R,2S)-bornane10,2-sultam0.35-hydrate, C(18)H(26)N(4)O(5)S(.)0.35H(2)O, have been characterized by spectroscopy and single- crystal X- ray analysis. Their structures are the result of C ss-re attack of the enophile on the double bond of the alkene.en
heal.publisherInternational Union of Crystallographyen
heal.journalNameActa Crystallographica Section C-Crystal Structure Communicationsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ

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