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https://olympias.lib.uoi.gr/jspui/handle/123456789/8122Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Adam, W. | en |
| dc.contributor.author | Bosio, S. G. | en |
| dc.contributor.author | Gogonas, E. P. | en |
| dc.contributor.author | Hadjiarapoglou, L. P. | en |
| dc.date.accessioned | 2015-11-24T16:39:08Z | - |
| dc.date.available | 2015-11-24T16:39:08Z | - |
| dc.identifier.issn | 0039-7881 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8122 | - |
| dc.rights | Default Licence | - |
| dc.subject | cycloaddition | en |
| dc.subject | 1,2,3-trisubstituted indanes | en |
| dc.subject | iodonium ylides | en |
| dc.subject | diastereoselective synthesis | en |
| dc.subject | ring contraction | en |
| dc.subject | iodonium ylides | en |
| dc.subject | stereochemistry | en |
| dc.title | A stereoselective and regioselective synthesis of trans,trans-configured 1,2,3-trisubstituted indanes: Cycloaddition of alkenes with iodonium ylides of beta-disulfones | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | <Go to ISI>://000178555700020 | - |
| heal.identifier.secondary | https://docs.google.com/file/d/0BxfLht5wJUEIYThmYmRiNTEtOWFhMi00ZWVhLWE3MjYtZmE4ZmZjNDQ4YjA5/edit?hl=en | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.publicationDate | 2002 | - |
| heal.abstract | The reaction of phenyliodonium-bis(sulfonyl) methylides alpha-gamma with alkenes 1 affords the multiply trisubstituted indanes 2 in moderate to good yields, through an unusual cycloaddition. The present stereoselective and regioselective cycloaddition provides a convenient preparative route to trans,trans-configured 1,2,3-trisubstituted indanes, in which the benzene ring derives from the arene-sulfonyl functionality of the bis(sulfonyl)iodonium ylide. The mechanistically puzzling structural feature is the fact (X-ray structure) that the para-methyl substituent of the original p-toluenesulfonyl group in the iodonium ylide is located in the C-6 position of the resulting indane benzene ring, that is, a meta relationship with respect to the original methylide carbon atom. | en |
| heal.journalName | Synthesis-Stuttgart | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Hadjiarapoglou-2002-A stereoselective and regioselective.pdf | 138.54 kB | Adobe PDF | View/Open Request a copy |
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