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  5. Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ
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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/8021
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dc.contributor.authorAra, I.en
dc.contributor.authorChaouche, N.en
dc.contributor.authorFornies, J.en
dc.contributor.authorFortuno, C.en
dc.contributor.authorKribii, A.en
dc.contributor.authorTsipis, A. C.en
dc.contributor.authorTsipis, C. A.en
dc.date.accessioned2015-11-24T16:38:15Z-
dc.date.available2015-11-24T16:38:15Z-
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8021-
dc.rightsDefault Licence-
dc.subjectphosphidoen
dc.subjecthydridoen
dc.subjecttrinuclear complexesen
dc.subjectbridging diphenylphosphido ligandsen
dc.subjectpalladium(ii)-platinum(ii) pentafluorophenyl complexesen
dc.subjectstereoselective oxidative additionen
dc.subjectray crystal-structureen
dc.subjectmolecular-structureen
dc.subjectx-rayen
dc.subjectelectronic-structuresen
dc.subjectchemical-shiftsen
dc.subjectreactivityen
dc.subjectclustersen
dc.titleFrom a 44-electron to a 48-electron trinuclear phosphido platinum complex: density functional study of [{(CF3)(PH3)Pt (mu-PH2)(mu-H)}(2)Pt] and [{(CF3)(PH3)Pt(mu-PH2)(mu-I)}(2)Pt] model compoundsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.ica.2004.04.006-
heal.identifier.secondary<Go to ISI>://000227667900006-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169304001987/1-s2.0-S0020169304001987-main.pdf?_tid=d1371e5438639b87873ab637cff35183&acdnat=1333112988_19b78dd59484f569c1364697b90f8c29-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.publicationDate2005-
heal.abstractTreatment of{{(C6F5)(PPh3)Pt(mu-PPh2))(mu-H)}(2)Pt] (1) with I-2 results in a complicated reaction from which [{(C6F5)(PPh3)Pt(mu-PPh2)(mu-1)}(2)Pt] (2) is obtained. The X-ray structure and F-19 and P-31 NMR spectra are given. Density functional theory (DFT) at the B3LYP level, using the LANL2DZ basis set, provides a satisfactory description of structural, bonding, electronic and related properties of [{(CF3)(PH3)Pt(mu-PH2)(mu-H)}(2)Pt] and [{(CF3)(PH3)Pt(mu-PH2)(mu-1)}(2)Pt} model compounds. The results unambiguously justify the predictions of the through-ring bonding required by the number of framework electrons and threw light on the bonding mechanism in the "{(Pt(mu-X)(mu-PH2)}(2)Pt" (X=H, 1) nuclear framework of the compounds. (c) 2004 Elsevier B.V. All rights reserved.en
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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