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dc.contributor.authorPanteli, Elenien
dc.contributor.authorSaratsioti, Panagiotaen
dc.contributor.authorStamatis, Haralamposen
dc.contributor.authorVoutsas, Epaminondasen
dc.date.accessioned2015-11-24T16:34:15Z-
dc.date.available2015-11-24T16:34:15Z-
dc.identifier.issn0021-9568-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/7781-
dc.rightsDefault Licence-
dc.titleSolubilities of Cinnamic Acid Esters in Organic Solventsen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primary10.1021/je9004382-
heal.identifier.secondaryhttp://dx.doi.org/10.1021/je9004382-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2009-
heal.abstractThe solubilities of three cinnamic acid esters, namely, methyl ferulate, methyl p-coumarate, and methyl sinapate, have been measured in tert-butanol, tert-pentanol, ethyl acetate, and n-hexane, at the temperature range of (303.15 to 321.15) K. It is shown that tert-pentanol is the best solvent for methyl p-coumarate and methyl ferulate and ethyl acetate for methyl sinapate, while the nonpolar n-hexane is the worst solvent. Using the experimentally measured solubilities, the thermodynamic properties of dissolution of the three esters have been calculated. To better understand the solubilization process, the melting temperatures and the enthalpies of fusion of the three esters were determined by differential scanning calorimetry. Finally, successful correlation of the experimental data was achieved with the UNIQUAC and the nonrandom two-liquid (NRTL) activity coefficient models.en
heal.publisherAmerican Chemical Societyen
heal.journalNameJournal of Chemical & Engineering Dataen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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