Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/30925
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dc.contributor.authorKonstas, Panagiotis – Spyridonen
dc.contributor.authorHela, Dimitraen
dc.contributor.authorGiannakas, Arisen
dc.contributor.authorKONSTANTINOU, IOANNISen
dc.contributor.authorAlbanis, Triantafyllosen
dc.date.accessioned2021-04-23T07:25:40Z-
dc.date.available2021-04-23T07:25:40Z-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/30925-
dc.identifier.urihttp://dx.doi.org/10.26268/heal.uoi.10759-
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/us/*
dc.subjectOrganophosphatesen
dc.subjectFlame retardantsen
dc.subjectTBEPen
dc.subjectPhotocatalysisen
dc.subjectOxidation pathwaysen
dc.titlePhotocatalytic degradation of organophosphate flame retardant TBEPen
heal.typejournalArticleel
heal.type.enJournal articleen
heal.type.elΆρθρο περιοδικούel
heal.secondaryTitlekinetics and identification of transformation products by orbitrap mass spectrometryen
heal.languageenel
heal.accesscampusel
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Τμήμα Χημείας.el
heal.publicationDate2019-03-21-
heal.bibliographicCitationΠεριλαμβάνει βιβλιογραφικές αναφορέςel
heal.abstractThe photocatalytic degradation of tris (2–butoxyethyl) phosphate (TBEP) flame retardant using visible light response catalysts TiO2 /V2O5, (N,F-doped)-TiO2/V2O5, and N-doped-SrTiO3 has been stu died by high-resolution orbitrap mass spectrometry. TBEP degra dation followed first-order kinetics with half-life values ranging between 9.8 and 83.5 min. N-doped-SrTiO3 was the catalyst with better photocatalytic performance while activity for TiO2/V2O5 composites followed the trend: N, F- TiO2/V2O5 > N-TiO2/V2O5> TiO2/V2O5. The identified degradation products (DPs) revealed hydroxylation, further oxidation and dealkylation as major degra dation pathways. Based on the identified DPs and scavenging experiments, • OH radical-mediated reactions can be considered for the degradation of TBEP using TiO2 and SrTiO3-based photo catalytic materials.en
heal.publisherTaylor & Francis Groupen
heal.journalNameInternational Journal of Environmental and Analytical Chemistry
heal.journalTypepeer-reviewedel
heal.fullTextAvailabilitytrue-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά). ΧΗΜ



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