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https://olympias.lib.uoi.gr/jspui/handle/123456789/19580Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kovala-Demertzi, D. | en |
| dc.contributor.author | Dokorou, V. | en |
| dc.contributor.author | Ciunik, M. | en |
| dc.contributor.author | Kourkoumelis, N. | en |
| dc.contributor.author | Demertzis, M. A. | en |
| dc.date.accessioned | 2015-11-24T19:00:42Z | - |
| dc.date.available | 2015-11-24T19:00:42Z | - |
| dc.identifier.issn | 0268-2605 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/19580 | - |
| dc.rights | Default Licence | - |
| dc.subject | anti-inflammatory drugs | en |
| dc.subject | mefenamic acid | en |
| dc.subject | organotin | en |
| dc.subject | structure | en |
| dc.subject | anti-tuberculosis agents | en |
| dc.subject | penta-coordinated molecules | en |
| dc.subject | diorganotin derivatives | en |
| dc.subject | drug interactions | en |
| dc.subject | diclofenac | en |
| dc.subject | adducts | en |
| dc.subject | mossbauer | en |
| dc.subject | behavior | en |
| dc.subject | tin(iv) | en |
| dc.subject | nmr | en |
| dc.title | Organotin mefenamic complexes - preparations, spectroscopic studies and crystal structure of a triphenyltin ester of mefenamic acid: novel anti-tuberculosis agents | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.primary | 10.1002/noc.308 | - |
| heal.identifier.secondary | <Go to ISI>://WOS:000176488200004 | - |
| heal.identifier.secondary | http://onlinelibrary.wiley.com/store/10.1002/aoc.308/asset/308_ftp.pdf?v=1&t=hhiqsvkf&s=d4f165c22d23e309cce6f6aa1143a9065a3fe078 | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών Υγείας. Τμήμα Ιατρικής | el |
| heal.publicationDate | 2002 | - |
| heal.abstract | The triphenyltin adduct of mefenamic acid, [SnPh3L] (1), the monophenyltin complex [PhSnOL](n) (2), and the dibutyltin complex [SnBu2L2] (3), where HL is 2-[bis(2,3-dimethylphenyl)amino]benzoic acid (mefenamic acid), have been prepared and structurally characterized by means of vibrational, H-1 and C-13 NMR spectroscopies. The crystal structure of I has been determined by X-ray crystallography. X-ray analysis revealed a pseudo-pentacoordinated structure containing Ph3Sn coordinated to the carboxylato group. The structural distortion is a displacement from the tetrahedron toward the trigonal bipyramid. Significant C-H-pi interactions and intramolecular hydrogen bonds stabilize the structure 1. The polar imino hydrogen atom participates in intramolecular hydrogen bonds. Complex I is self-assembled via C - H-pi and stacking interactions. Vibrational and NMR data are discussed in terms of the crystal structure and the proposed structures for 1-3. Compounds 1 and 3 were tested for antimycobacterial activity against Mycobacterium tuberculosis H37Rv. Copyright (C) 2002 John Wiley Sons, Ltd. | en |
| heal.journalName | Applied Organometallic Chemistry | en |
| heal.journalType | peer-reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά) - ΙΑΤ | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Kovala-Demertzi-2002-Organotin mefenamic.pdf | 185.4 kB | Adobe PDF | View/Open Request a copy |
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