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dc.contributor.authorElmahdy, M. M.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorKastler, M.en
dc.contributor.authorMullen, K.en
dc.date.accessioned2015-11-24T18:40:27Z-
dc.date.available2015-11-24T18:40:27Z-
dc.identifier.issn0953-8984-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17623-
dc.rightsDefault Licence-
dc.subjectelastic neutron-scatteringen
dc.subjectdiscotic liquid-crystalsen
dc.subjectcharge-carrier mobilityen
dc.subjectglass-transitionen
dc.subjectdielectric-spectroscopyen
dc.subjectsupramolecular orderen
dc.subjecttriphenyleneen
dc.subjectphaseen
dc.subjectorganizationen
dc.subjectderivativesen
dc.titleMolecular dynamics of branched hexaalkyl hexa-peri-hexabenzocoronenesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1088/0953-8984/20/24/244105-
heal.identifier.secondary<Go to ISI>://000256556400006-
heal.identifier.secondaryhttp://iopscience.iop.org/0953-8984/20/24/244105/pdf/0953-8984_20_24_244105.pdf-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2008-
heal.abstractThe molecular dynamics of discotic liquid crystalline hexa-peri-hexabenzocoronenes (HBC-C(10,6) and HBC-C(14,10)) with long alkyl side chains branched in close vicinity to the HBC aromatic core were studied by dielectric spectroscopy. The two compounds display a weak dipolar relaxation (a-process) manifested by a Vogel-Fulcher-Tammann (VFT) dependence and have almost the same glass temperature (similar to 215 K) in excellent agreement with the value from differential scanning calorimetry. The origin of this process is the freezing of the in-plane disc rotation. Controlled experiments revealed that the weak dipole moment associated with the a-process is due to oxidation.en
heal.journalNameJournal of Physics-Condensed Matteren
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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