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dc.contributor.authorPapadopoulos, P.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorChi, C.en
dc.contributor.authorWegner, G.en
dc.date.accessioned2015-11-24T18:40:27Z-
dc.date.available2015-11-24T18:40:27Z-
dc.identifier.issn0021-9606-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17622-
dc.rightsDefault Licence-
dc.subjectliquid-crystalline polyfluoreneen
dc.subjectpolarized electroluminescenceen
dc.subjectconjugated polymersen
dc.subjectamorphous materialsen
dc.subjectblue-lighten
dc.subjectemissionen
dc.subjectrelaxationen
dc.titleMolecular dynamics of oligofluorenes: A dielectric spectroscopy investigationen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1063/1.1637339-
heal.identifier.secondary<Go to ISI>://000188498400033-
heal.identifier.secondaryhttp://link.aip.org/getpdf/servlet/GetPDFServlet?filetype=pdf&id=JCPSA6000120000005002368000001-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2004-
heal.abstractThe molecular dynamics were investigated in a series of "defect-free" oligofluorenes up to the polymer by dielectric spectroscopy (DS). The method is very sensitive to the presence of keto "defects" that when incorporated on the backbone give rise to poor optical and electronic properties. Two dielectrically active processes were found (beta and alpha process). The latter process (alpha) displays strongly temperature dependent relaxation times and temperature- and molecular weight-dependent spectral broadening associated with intramolecular correlations. The glass temperature (T-g) obeys the Fox-Flory equation and the polymer T-g is obtained by DS at 332 K. The effective dipole moment associated with the alpha process is 0.27+/-0.03 D. (C) 2004 American Institute of Physics.en
heal.journalNameJournal of Chemical Physicsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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