Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/17614
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dc.contributor.authorDouvalis, A. P.en
dc.contributor.authorPapaefthymiou, V.en
dc.contributor.authorMoukarika, A.en
dc.contributor.authorBakas, T.en
dc.contributor.authorKallias, G.en
dc.date.accessioned2015-11-24T18:40:24Z-
dc.date.available2015-11-24T18:40:24Z-
dc.identifier.issn0953-8984-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17614-
dc.rightsDefault Licence-
dc.subjectironen
dc.titleMossbauer and magnetization studies of Fe2BO4en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000085908500008-
heal.identifier.secondaryhttp://iopscience.iop.org/0953-8984/12/2/307/pdf/0953-8984_12_2_307.pdf-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2000-
heal.abstractPolycrystalline Fe2BO4 prepared by solid-state reaction was investigated over a wide temperature range using Mossbauer spectroscopy and magnetization and resistivity measurements. The Mossbauer data below 270 K reveal four iron sites (two Fe2+ and two Fe3+) in a 1:1:1:1 ratio. Above this temperature, electron delocalization sets in between the divalent-trivalent iron ions and up to 400 K both delocalized and localized iron states are observed. The magnetization and Mossbauer data indicate that this oxoborate mixed-valence system is an L-type ferrimagnet below T-c = 155 K, with the iron atoms in each sublattice having different point symmetries and different magnetic interactions. The resistivity data show the first-order nature of the charge-ordering transition (T-co = 316 K).en
heal.journalNameJournal of Physics-Condensed Matteren
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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