Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/17575
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dc.contributor.authorPapageorgopoulos, C. A.en
dc.contributor.authorKamaratos, M.en
dc.contributor.authorSaltas, V.en
dc.contributor.authorJaegermann, W.en
dc.contributor.authorPettenkofer, C.en
dc.contributor.authorTonti, D.en
dc.date.accessioned2015-11-24T18:40:11Z-
dc.date.available2015-11-24T18:40:11Z-
dc.identifier.issn0218-625X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17575-
dc.rightsDefault Licence-
dc.subjectinduced deintercalationen
dc.subjectintercalationen
dc.subjectadsorptionen
dc.subjectw(110)en
dc.subjectmetalen
dc.subjectbr-2en
dc.titleNa and Cl-2 interaction on 1T and 2H-TaSe2(0001) surfacesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000077249200008-
heal.identifier.secondaryhttp://www.worldscinet.com/srl/05/0505/S0218625X98001353.html-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate1998-
heal.abstractLn this paper we study the interaction of Cl-2 and Na on 1T-TaSe2 and 2H-TaSe2(0001) surfaces in the temperature range of 100-300 K. The experiments are performed in UHV with the use of LEED and SXPS by synchrotron radiation measurements. Deposition of Na on Cia-covered 1T-TaSe2 at 100 K forms initially a Na-Cl-2(-) which with increasing temperature to 300 K leads to NaCl formation. Adsorption of Cl-2 on Na-intercalated 1T and PH-TaSe2 surfaces at 100 K forms Cl-2 multilayers. The first Cl-2 layer, in contact with the substrate, interacts with the Na near the surface and forms NaCl2-. Warming up to 300 K leads to partial desorption of Cia, while the remaining chlorine interacts strongly with Na, causing the deintercalation of Na to the surface in the tendency to form NaCl. The intercalation-deintercalation process takes place across the van der Waals planes and it is much faster on 2H than on 1T-TaSe2, which is attributed to the different crystal structure of 2H and 1T of TaSe2.en
heal.journalNameSurface Review and Lettersen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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