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dc.contributor.authorCohen, S.en
dc.contributor.authorLiontos, I.en
dc.contributor.authorBolovinos, A.en
dc.contributor.authorLyras, A.en
dc.contributor.authorBenech, S.en
dc.contributor.authorBachau, H.en
dc.date.accessioned2015-11-24T18:39:42Z-
dc.date.available2015-11-24T18:39:42Z-
dc.identifier.issn0953-4075-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17487-
dc.rightsDefault Licence-
dc.subjectquantum-defect theoryen
dc.subjectlaser optogalvanic spectroscopyen
dc.subjecteigenchannel r-matrixen
dc.subjectautoionizing statesen
dc.subjecttheoretical-analysisen
dc.subject3-photon ionizationen
dc.subjectsingle-photonen
dc.subjectenergy-levelsen
dc.subjectneutral caen
dc.subjectexcitationen
dc.titleTwo-photon ionization spectra of calcium above the 4s(1/2) thresholden
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1088/0953-4075/39/12/006-
heal.identifier.secondary<Go to ISI>://000239306700009-
heal.identifier.secondaryhttp://iopscience.iop.org/0953-4075/39/12/006/pdf/0953-4075_39_12_006.pdf-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2006-
heal.abstractTwo-photon ionization of ground state calcium is investigated both experimentally and theoretically in the 374 - 323 nm spectral range. The spectra are dominated by the presence of the 4p(2) S-1(0) perturber and by members of even parity 3dnd J = 0, 2 (4 <= n <= 10) and 3dns J = 2 (6 <= n <= 12) autoionizing Rydberg series, the latter appearing as window resonances. No single-photon resonances are observed. The majority of recorded lines are identified using older stepwise spectroscopic data while there is a number of newly discovered low-lying members. The two previously unobserved 3dns, n <= 12, series members are treated using a semi-empirical multichannel quantum defect theory (MQDT) model. Moreover, the low-lying part of the observed predominantly singlet spectrum is fairly well reproduced by theoretical calculations, combining a configuration interaction approach with B-splines basis functions and neglecting relativistic effects. The agreement between theory and experiment becomes less satisfactory as we move towards higher lying resonances dominated by singlet-triplet mixing effects, which are evident in the experimental data while neglected in the calculations.en
heal.journalNameJournal of Physics B-Atomic Molecular and Optical Physicsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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