Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/17414
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dc.contributor.authorFoulias, S. D.en
dc.contributor.authorPerdikis, A.en
dc.contributor.authorVlachos, D.en
dc.date.accessioned2015-11-24T18:39:16Z-
dc.date.available2015-11-24T18:39:16Z-
dc.identifier.issn0218-625X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17414-
dc.rightsDefault Licence-
dc.subjectauger electron spectroscopy (aes)en
dc.subjectwork function (wf)en
dc.subjectsurface carbideen
dc.subjecttungsten carbideen
dc.subjectalkali depositionen
dc.subjectoxygen adsorptionen
dc.subjectadsorption kineticsen
dc.subjectsurface segregationen
dc.subjecttransition metal carbidesen
dc.subjectcarbon diffusionen
dc.subjecttungsten carbideen
dc.subjectelectronic-propertiesen
dc.subjectcatalytic behavioren
dc.subjectsurfaceen
dc.subjectw(100)en
dc.subjecttransitionen
dc.subjecto-2en
dc.subjectphotoemissionen
dc.subjectoverlayersen
dc.subjectacetyleneen
dc.titleOxygen and potassium adsorption on a carbide-modified stepped-W(100) in contact with the carbon solid solution: An AES and WF study at 300 K and at elevated temperaturesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000237301600019-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2005-
heal.abstractThe adsorption of oxygen and potassium on the two-phase system: carbide-modified stepped-W(100) surface (CMT) in contact with the solid solution of carbon in bulk tungsten, was investigated by AES and WF measurements. The CMT surface shows metallic behavior judging from its interaction with K. The expected dissociative adsorption of oxygen appears to occur with 1-theta kinetics, possibly via a molecularly chemisorbed state. The "dispersed phase two-phase" model is clearly applicable when oxygen adsorbs on the K-pre-covered carbide. The initial sticking coefficient of oxygen increases drastically from the dispersed to the condensed phase, at least four-fold with respect to so on the clean carbide. It is proposed that this two-phase carbon system can be advantageous compared with the bulk carbide since it can easily regenerate the surface if the latter is depleted from carbon.en
heal.journalNameSurface Review and Lettersen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)



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