Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/17109
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dc.contributor.authorWewerka, A.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorPakula, T.en
dc.contributor.authorStelzer, F.en
dc.date.accessioned2015-11-24T18:35:33Z-
dc.date.available2015-11-24T18:35:33Z-
dc.identifier.issn0024-9297-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17109-
dc.rightsDefault Licence-
dc.subjectpolymersen
dc.subjectblocken
dc.subjecttransitionen
dc.subjectbehavioren
dc.subjectgraften
dc.titleSide-chain liquid-crystalline homopolymers and copolymers. Structure and rheologyen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Ma010944o-
heal.identifier.secondary<Go to ISI>://000171981500030-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ma010944o-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2001-
heal.abstractWe report on the structure and the viscoelastic properties of two side-chain liquid-crystalline polymers with different spacer length in the melt and fiber states and of their Copolymers with a semicrystalline block. Optical microscopy, X-ray scattering, and differential scanning calorimetry are employed for the structure investigation and rheology for the dynamics. The smectic and nematic liquid-crystalline polymers exhibit non-Newtonian low-frequency response and violate the empirical principle of time-temperature superposition with the effect being more pronounced in the former. Fibers drawn from the melt exhibit significantly different structure from the melt samples. In the diblock copolymer composed of smectic/crystalline blocks, the strong first-order isotropic-to-smectic transition induces the weak disorder-to-lamellar transition between the dissimilar blocks in the diblock.en
heal.journalNameMacromoleculesen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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