Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/16935
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dc.contributor.authorWu, X. N.en
dc.contributor.authorFrancisco, M.en
dc.contributor.authorRak, Z.en
dc.contributor.authorBakas, T.en
dc.contributor.authorMahanti, S. D.en
dc.contributor.authorKanatzidis, M. G.en
dc.date.accessioned2015-11-24T18:34:26Z-
dc.date.available2015-11-24T18:34:26Z-
dc.identifier.issn0022-4596-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16935-
dc.rightsDefault Licence-
dc.subjectintermetallicsen
dc.subjectflux synthesisen
dc.subjectband calculationsen
dc.subjectcrystal-structureen
dc.subjectneutron-diffractionen
dc.subjectlda+u methoden
dc.subjectla-nden
dc.subjectaluminumen
dc.subjectreen
dc.subjectsmen
dc.subjectcompounden
dc.subjectbehavioren
dc.subjectgalliumen
dc.titleSynthesis, magnetism and electronic structure of YbNi(2-x)Fe(x)Al(8) (x=0.91) isolated from Al fluxen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.jssc.2008.08.029-
heal.identifier.secondary<Go to ISI>://000261517800013-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0022459608004702/1-s2.0-S0022459608004702-main.pdf?_tid=598be3217f17009e56640edddee2bd9c&acdnat=1334136541_160c3acc9c3c5051ac26742b5d6da7dd-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2008-
heal.abstractThe combination of ytterbium, nickel, iron in liquid aluminum resulted in the formation of the new intermetallic compound YbNi(2-x)Fe(x)Al(8) (x = 0.91) which adopts the CaCO(2)Al(8) structure type with a = 14.458(3) angstrom, b = 12.455(3) angstrom, c = 3.9818(8) angstrom and space group Pbam. Its resistivity drops with decreasing temperature, saturating to a constant value at lower temperatures. Above 50 K, the inverse magnetic susceptibility data follows Curie-Weiss Law, with a calculated mu(eff) = 2.19 mu(B). Although the observed reduced moment in magnetic susceptibility measurement suggests that the Yb ions in this compound are of mixed-valent nature, ab initio electronic structure calculations within density functional theory using LDA+U approximation give an f(13) configuration in the ground state. (C) 2008 Elsevier Inc. All rights reserved.en
heal.journalNameJournal of Solid State Chemistryen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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