Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/16738
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dc.contributor.authorFuss, W.en
dc.contributor.authorKosmidis, C.en
dc.contributor.authorSchmid, W. E.en
dc.contributor.authorTrushin, S. A.en
dc.date.accessioned2015-11-24T18:33:28Z-
dc.date.available2015-11-24T18:33:28Z-
dc.identifier.issn0009-2614-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16738-
dc.rightsDefault Licence-
dc.subjecttransition-state dynamicsen
dc.subjectconical intersectionsen
dc.subjectvibrational coherenceen
dc.subjectcharge-transferen
dc.subjectab-initioen
dc.subjectphotoisomerizationen
dc.subjectisomerizationen
dc.subjectpicoseconden
dc.subjectdependenceen
dc.subjectmoleculesen
dc.titleThe lifetime of the perpendicular minimum of cis-stilbene observed by dissociative intense-laser field ionizationen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDOI 10.1016/j.cplett.2003.12.114-
heal.identifier.secondary<Go to ISI>://000189087800016-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0009261404000168/1-s2.0-S0009261404000168-main.pdf?_tid=1bfae30203b01668c32eee641bd0d3f2&acdnat=1334229093_8b7c6c991e8a0d04202deaf63d78afad-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2004-
heal.abstractCis-stilbene was excited by one photon at 270 nm in the gas phase and then probed by ionization at infrared wavelengths (810 and 2100 nm), recording the delay-time dependent mass spectra. We found not only a decay of 300 fs, previously assigned to departure from the fluorescent region, but also a second time constant (160 A), probably representing departure from the 'perpendicular minimum' (excited state with twisted ethene part). In addition, two coherent oscillations (periods 140 and approximate to600 fs) were found in the 300-fs window. We discuss their implications for the initial motion and point out the importance of vibronic interaction of excited states. (C) 2004 Elsevier B.V. All rights reserved.en
heal.journalNameChemical Physics Lettersen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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