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https://olympias.lib.uoi.gr/jspui/handle/123456789/16735Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lalia-Kantouri, M. | en |
| dc.contributor.author | Papadopoulos, C. D. | en |
| dc.contributor.author | Hatzidimitriou, A. C. | en |
| dc.contributor.author | Bakas, T. | en |
| dc.contributor.author | Pachini, S. | en |
| dc.date.accessioned | 2015-11-24T18:33:26Z | - |
| dc.date.available | 2015-11-24T18:33:26Z | - |
| dc.identifier.issn | 0044-2313 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/16735 | - |
| dc.rights | Default Licence | - |
| dc.subject | iron | en |
| dc.subject | solid-state structures | en |
| dc.subject | magnetic properties | en |
| dc.subject | electrochemistry | en |
| dc.subject | mossbauer spectroscopy | en |
| dc.subject | molecular-structures | en |
| dc.subject | addition-compounds | en |
| dc.subject | crystal | en |
| dc.subject | salicylaldehydes | en |
| dc.subject | mossbauer | en |
| dc.subject | clusters | en |
| dc.subject | exchange | en |
| dc.subject | behavior | en |
| dc.subject | fe | en |
| dc.title | A Trinuclear Iron(III) Complex Containing the Semi-Cubane [Fe(3)(mu(3)-O)](7+) Core: Structural, Spectroscopic, Magnetic and Electrochemical Study | en |
| heal.type | journalArticle | - |
| heal.type.en | Journal article | en |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.identifier.secondary | <Go to ISI>://000276497000019 | - |
| heal.identifier.secondary | http://onlinelibrary.wiley.com/store/10.1002/zaac.200900292/asset/531_ftp.pdf?v=1&t=h0w66z1c&s=38da21c716d3bcecf7c1e88122910bca326f3ec1 | - |
| heal.language | en | - |
| heal.access | campus | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.publicationDate | 2010 | - |
| heal.abstract | A trinuclear iron(III) oxo-centered complex [Fe(3)(mu(3)-O)(3-OCH(3)-salnec)(3)]OH center dot 5H(2)O was synthesized and characterized as cluster containing the semi-cubane [Fe(3)(mu(3)-O)](7+) core. The central oxygen atom is bridging the three iron(111) ions, which form an equilateral triangle with an average edge of -3.00 angstrom as it was deduced from X-ray diffraction studies. The new tetradentate ligand 3-OCH(3)-salnecH(2) = 1-[1-hydroxy-2(9'-methyl-1,10'-phenanthrolin-2-yl)ethyl]-3-methoxyphenol-2, was generated "in situ" during the synthesis process as a product of the addition reaction between the starting ligands 2,9-dimethyl-phenanthroline(neoc) and 3-methoxy-salicylaldehyde(3-OCH(3)-saloH(2)), in the presence of sodium methoxide and Fe(3+). Variable-temperature magnetic measurements indicate antiferromagnetic exchange interactions between the iron(III) ions in the cluster. Additionally, spectroscopic (IR, UV/Vis, Mossbauer, EPR) and electrochemical studies (CV) are presented and discussed. | en |
| heal.journalName | Zeitschrift Fur Anorganische Und Allgemeine Chemie | en |
| heal.journalType | peer reviewed | - |
| heal.fullTextAvailability | TRUE | - |
| Appears in Collections: | Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά) | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Lalia-Kantouri-2010-A Trinuclear Iron(II.pdf | 570.47 kB | Adobe PDF | View/Open Request a copy |
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