Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/16309
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dc.contributor.authorMierzwa, M.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorWewerka, A.en
dc.date.accessioned2015-11-24T18:29:53Z-
dc.date.available2015-11-24T18:29:53Z-
dc.identifier.issn0022-3093-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16309-
dc.rightsDefault Licence-
dc.subjectrelaxationen
dc.subjectbehavioren
dc.titleDynamics of diblock co-polymers composed from a side-chain liquid-crystalline and a crystallizable block. A dielectric spectroscopy studyen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000176261600020-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2002-
heal.abstractWe have investigated the dynamics in two side-chain liquid crystalline derivatives of poly(norbornene diethylester) and their co-polymers with the semicrystalline block polyoctene by dielectric spectroscopy within the temperature range 170-433 K. The structure investigation revealed the formation of a nematic and a smectic A phase, respectively, in the Side-chain polymer liquid crystals (SC-PLC) homopolymers and the co-polymers with the shorter and longer spacers, respectively. Multiple relaxation processes were found in both the homopolymers and the co-polymers. The dynamics in the co-polymer with the longer spacer forming the smectic phase were reminiscent to the corresponding SC-PLC homopolymer, indicating strong microphase separation. However, in the co-polymer with the shorter spacer of the SC-PLC block forming the nematic phase, there was evidence for dynamic mixing between the dissimilar blocks which explains the reduced transition temperature of the SC-PLC block and the absence of crystallization of the polyoctene block. (C) 2002 Elsevier Science B.V. All rights reserved.en
heal.journalNameJournal of Non-Crystalline Solidsen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)



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