Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/16217
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dc.contributor.authorPapadopoulos, P.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorSchnell, I.en
dc.contributor.authorLieberwirth, I.en
dc.contributor.authorNguyen, T. Q.en
dc.contributor.authorKlok, H. A.en
dc.date.accessioned2015-11-24T18:29:02Z-
dc.date.available2015-11-24T18:29:02Z-
dc.identifier.issn1525-7797-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16217-
dc.rightsDefault Licence-
dc.subjectelectric dipole momenten
dc.subjectblock-copolymersen
dc.subjectsolid-stateen
dc.subjectpolypeptide solutionsen
dc.subjectdiblock copolymersen
dc.subjectmolecular-dynamicsen
dc.subjectdielectric-dispersionen
dc.subjectglass-transitionen
dc.subjectgamma-benzylen
dc.subjectroden
dc.titleThermodynamic confinement and alpha-helix persistence length in poly(gamma-benzyl-L-glutamate)-b-poly(dimethyl siloxane)-b-poly(gamma-benzyl-L-glutamate) triblock copolymersen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Bm050772t-
heal.identifier.secondary<Go to ISI>://000235538600032-
heal.identifier.secondaryhttp://pubs.acs.org/doi/abs/10.1021/bm050772t-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2006-
heal.abstractThe structure and the associated dynamics of a series of poly(y-benzyl-L-glutamate)-b-poly(dimethyl siloxane)b-poly(y-benzyl-L-glutamate) (PBLG-b-PDMS-b-PBLG) triblock copolymers were investigated using small- and wide-angle X-ray scattering, NMR, transmission electron microscopy, and dielectric spectroscopy, respectively. The structural analysis revealed phase separation in the case of the longer blocks with defected alpha-helical segments embedded within the block copolymer nanodomains. The alpha-helical persistence length was found to depend on the degree of segregation; thermodynamic confinement and chain stretching results in the partial annihilation of helical defects.en
heal.journalNameBiomacromoleculesen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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