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dc.contributor.authorKarras, G.en
dc.contributor.authorDanakas, S.en
dc.contributor.authorKosmidis, C.en
dc.date.accessioned2015-11-24T18:28:02Z-
dc.date.available2015-11-24T18:28:02Z-
dc.identifier.issn1089-5639-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16114-
dc.rightsDefault Licence-
dc.subjectmultiphoton ionizationen
dc.subjectmethyl-iodideen
dc.subjectultrafast dynamicsen
dc.subjectpicoseconden
dc.subjectphotodissociationen
dc.subjectdissociationen
dc.subjectenergyen
dc.subjectdimeren
dc.subjectch3ien
dc.subjectno2en
dc.titleFormation of Molecular Halide Ions from Alkyl-Halide Clusters Irradiated by ps and fs Laser Pulsesen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Jp2015947-
heal.identifier.secondary<Go to ISI>://000289824500007-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/jp2015947-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2011-
heal.abstractWe report on the interaction of alkyl-halide clusters with 35 ps and 20 fs laser pulses at lambda = 266, 532, and 1064 nm and 400 and 800 nm, respectively. Particularly, we examine by means of time-of-flight mass spectrometry the intracluster photochemical processes, which give rise to the formation of molecular halogen ions. The efficiency of molecular halogen ion formation is found to depend strongly on the laser wavelength and pulse duration. The ionization/excitation schemes involve in both cases the multiphoton absorption by the clusters and the combined action of the laser and the intracluster electric field. Intracluster energy transfer processes seem to have a significant contribution to the molecular halogen ion formation in the ps domain, while in the Is region, this is probably facilitated by a rescattering process and/or by photon absorption. A physical mechanism for the interpretation of our experimental results is proposed.en
heal.journalNameJournal of Physical Chemistry Aen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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