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Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/16103
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dc.contributor.authorDuran, H.en
dc.contributor.authorSteinhart, M.en
dc.contributor.authorButt, H. J.en
dc.contributor.authorFloudas, G.en
dc.date.accessioned2015-11-24T18:27:51Z-
dc.date.available2015-11-24T18:27:51Z-
dc.identifier.issn1530-6984-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16103-
dc.rightsDefault Licence-
dc.subjectnucleationen
dc.subjectconstrained crystallizationen
dc.subjectnanoporous aluminaen
dc.subjectisotactic polypropyleneen
dc.subjectcalorimetryen
dc.subjectanodic porous aluminaen
dc.subjectpolymer crystallizationen
dc.subjectisothermal crystallizationen
dc.subjectcylindrical nanoporesen
dc.subjectsegmental dynamicsen
dc.subjectacid-solutionen
dc.subjectphase-changeen
dc.subjectpolypropyleneen
dc.subjectkineticsen
dc.subjectcrystalsen
dc.titleFrom Heterogeneous to Homogeneous Nucleation of Isotactic Poly(propylene) Confined to Nanoporous Aluminaen
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.primaryDoi 10.1021/Nl200153c-
heal.identifier.secondary<Go to ISI>://000289341500048-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/nl200153c-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2011-
heal.abstractThe crystallization of highly isotactic polypropylene confined in self-ordered nanoporous alumina is studied by differential scanning calorimetry. A transformation from a predominantly heterogeneous to predominantly homogeneous nucleation takes place if the pore diameter is smaller than 65 nm. Crystallization is suppressed with decreasing pore size, and the absence of nucleation below 20 nm pores indicates the critical nucleus size. The results reported here might enhance the understanding of nanocomposites containing semicrystalline polymers and reveal design criteria for polymeric nanofibers with tailored mechanical and optical pioperties.en
heal.journalNameNano Letten
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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