Please use this identifier to cite or link to this item: https://olympias.lib.uoi.gr/jspui/handle/123456789/15939
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dc.contributor.authorPhilis, J. G.en
dc.date.accessioned2015-11-24T18:26:43Z-
dc.date.available2015-11-24T18:26:43Z-
dc.identifier.issn0022-2860-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/15939-
dc.rightsDefault Licence-
dc.subjectn-methylpyrroleen
dc.subjectmethyl torsional transitionsen
dc.subjectrempien
dc.subjectelectronic excitationen
dc.subjectpyrroleen
dc.subjectfuranen
dc.subjectstatesen
dc.subjectcyclopentadieneen
dc.subjectspectraen
dc.subjectabsorptionen
dc.subjectmoleculesen
dc.subjectbanden
dc.subjects-0en
dc.titleTorsional features in the (3s)S-1 <- S-0 transition of N-methylpyrrole and C4D4NCH3en
heal.typejournalArticle-
heal.type.enJournal articleen
heal.type.elΆρθρο Περιοδικούel
heal.identifier.secondary<Go to ISI>://000183424200075-
heal.languageen-
heal.accesscampus-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.publicationDate2003-
heal.abstractThe one-photon and two-photon S-1 <-- S-0 REMPI spectra of jet-cooled N-methylpyrrole-ring-d(4) (C4D4NCH3, NMPd4) were studied and compared to the corresponding spectra of N-methylpyrrole (C4H4NCH3, NMP). This electronic transition is the electric dipole forbidden 3sA(2) <-- A(1) Rydberg excitation. The transition is allowed in two-photon spectroscopy and the origin was found in the two-photon spectra at 41,193 and 42,015 cm(-1) for NMP and NMPd4, respectively. Exactly the same low-frequency pattern is present close to the absent origin in the one-photon spectra of NMP and NMPd4. The assignment of these features to methyl internal rotational transitions is confirmed. (C) 2003 Elsevier Science B.V. All rights reserved.en
heal.journalNameJournal of Molecular Structureen
heal.journalTypepeer reviewed-
heal.fullTextAvailabilityTRUE-
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